4-[2-(4-Pyridyl)ethyl]pyridinium nitrate tri hydrate

Filipe A. Almeida Paz; Yaroslav Z. Khimyak; Jacek Klinowski

doi:10.1107/S1600536803000783

4-[2-(4-Pyridyl)ethyl]pyridinium nitrate tri hydrate

Filipe A. Almeida Paz
, Yaroslav Z. Khimyak
, Jacek Klinowski

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, C₁₂H₁₃N₂ ⁺·NO₃^-·3H₂O [where C₁₂H₁₃N₂⁺ is the monoprotonated form of 1,2-bis(4-pyridyl)-ethane (BPEH⁺)] is monoclinic, space group P2₁/c, and contains two empirical formulae in the asymmetric unit. The compound has cationic [BPEH]_nⁿ⁺ organic layers, alternating in the b direction with anionic [(NO₃)·3H ₂O]_n^n- inorganic layers. Hydrogen bonds between 4-pyridyl and 4-pyridinium groups, and between nitrate ions and water molecules, give rise to chains and two-dimensional hydrogen-bonding networks, respectively.

Original language	English
Pages (from-to)	o132-o134
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	2
Early online date	17 Jan 2003
DOIs	https://doi.org/10.1107/S1600536803000783
Publication status	Published - Feb 2003
Externally published	Yes

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title = "4-[2-(4-Pyridyl)ethyl]pyridinium nitrate tri hydrate",

abstract = "The title compound, C12H13N2 +·NO3-·3H2O [where C12H13N2+ is the monoprotonated form of 1,2-bis(4-pyridyl)-ethane (BPEH+)] is monoclinic, space group P21/c, and contains two empirical formulae in the asymmetric unit. The compound has cationic [BPEH]nn+ organic layers, alternating in the b direction with anionic [(NO3)·3H 2O]nn- inorganic layers. Hydrogen bonds between 4-pyridyl and 4-pyridinium groups, and between nitrate ions and water molecules, give rise to chains and two-dimensional hydrogen-bonding networks, respectively.",

author = "\{Almeida Paz\}, \{Filipe A.\} and Khimyak, \{Yaroslav Z.\} and Jacek Klinowski",

year = "2003",

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pages = "o132--o134",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - 4-[2-(4-Pyridyl)ethyl]pyridinium nitrate tri hydrate

AU - Almeida Paz, Filipe A.

AU - Khimyak, Yaroslav Z.

AU - Klinowski, Jacek

PY - 2003/2

Y1 - 2003/2

N2 - The title compound, C12H13N2 +·NO3-·3H2O [where C12H13N2+ is the monoprotonated form of 1,2-bis(4-pyridyl)-ethane (BPEH+)] is monoclinic, space group P21/c, and contains two empirical formulae in the asymmetric unit. The compound has cationic [BPEH]nn+ organic layers, alternating in the b direction with anionic [(NO3)·3H 2O]nn- inorganic layers. Hydrogen bonds between 4-pyridyl and 4-pyridinium groups, and between nitrate ions and water molecules, give rise to chains and two-dimensional hydrogen-bonding networks, respectively.

AB - The title compound, C12H13N2 +·NO3-·3H2O [where C12H13N2+ is the monoprotonated form of 1,2-bis(4-pyridyl)-ethane (BPEH+)] is monoclinic, space group P21/c, and contains two empirical formulae in the asymmetric unit. The compound has cationic [BPEH]nn+ organic layers, alternating in the b direction with anionic [(NO3)·3H 2O]nn- inorganic layers. Hydrogen bonds between 4-pyridyl and 4-pyridinium groups, and between nitrate ions and water molecules, give rise to chains and two-dimensional hydrogen-bonding networks, respectively.

UR - https://www.scopus.com/pages/publications/0041848757

U2 - 10.1107/S1600536803000783

DO - 10.1107/S1600536803000783

M3 - Article

AN - SCOPUS:0041848757

SN - 1600-5368

VL - 59

SP - o132-o134

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

4-[2-(4-Pyridyl)ethyl]pyridinium nitrate tri hydrate

Abstract

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