A fluorophosphate-based inverse Keggin structure

John Fielden; Kyle Quasdorf; Leroy Cronin; Paul Kögerler

doi:10.1039/c2dt30501a

A fluorophosphate-based inverse Keggin structure

John Fielden, Kyle Quasdorf, Leroy Cronin, Paul Kögerler

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

Original language	English
Pages (from-to)	9876-9878
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	33
DOIs	https://doi.org/10.1039/c2dt30501a
Publication status	Published - 7 Sep 2012

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10.1039/c2dt30501a

Cite this

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title = "A fluorophosphate-based inverse Keggin structure",

abstract = "An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.",

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AU - Fielden, John

AU - Quasdorf, Kyle

AU - Cronin, Leroy

AU - Kögerler, Paul

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Y1 - 2012/9/7

N2 - An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

AB - An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

U2 - 10.1039/c2dt30501a

DO - 10.1039/c2dt30501a

M3 - Article

VL - 41

SP - 9876

EP - 9878

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 33

ER -