A Homochiral 2D Copper(II) Coordination Framework

John Fielden, Kyle Quasdorf, Arkady Ellern, Paul Kögerler

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Reaction of copper(II) salts with (S)-phenylethylaminodiacetate [(S)-peadaa] results in the 2D coordination network (S)-[Cu(peadaa)]n (space group P21), which displays an unusual Cu···Cu connectivity mode. Solid-state circular dichroism (CD) indicates a strong interaction between the ligand chiral centre and the metal centres, whereas magnetic measurements show both antiferromagnetic coupling and strong ligand field effects. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Original languageEnglish
Pages (from-to)717-720
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Volume2009
Issue number6
Early online date16 Jan 2009
DOIs
Publication statusPublished - Feb 2009

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