A mesogenic triphenylene-perylene-triphenylene triad

Xiangfei Kong; Zhiqun He; Yinning Zhang; Linping Mu; Chunjun Liang; Bo Chen; Xiping Jing; Andrew N. Cammidge

doi:10.1021/ol103018v

A mesogenic triphenylene-perylene-triphenylene triad

Xiangfei Kong
, Zhiqun He
, Yinning Zhang
, Linping Mu
, Chunjun Liang
, Bo Chen
, Xiping Jing
, Andrew N. Cammidge

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP10 showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1% PBITP10 is homogeneous and liquid crystalline.

Original language	English
Pages (from-to)	764-767
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	4
DOIs	https://doi.org/10.1021/ol103018v
Publication status	Published - 2011

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10.1021/ol103018v

Cite this

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abstract = "A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP10 showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1\% PBITP10 is homogeneous and liquid crystalline.",

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AU - Kong, Xiangfei

AU - He, Zhiqun

AU - Zhang, Yinning

AU - Mu, Linping

AU - Liang, Chunjun

AU - Chen, Bo

AU - Jing, Xiping

AU - Cammidge, Andrew N.

PY - 2011

Y1 - 2011

N2 - A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP10 showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1% PBITP10 is homogeneous and liquid crystalline.

AB - A straightforward synthesis of triphenylene-perylene-triphenylene triad structures has been achieved by using versatile triphenylene intermediates bearing a single oxyalkyl amine side chain. Among these, PBITP10 showed a stable columnar mesophase implying favorably matched core-core separations in the structure. Importantly, the triad can be used as a vehicle for doping columnar triphenylene matrices with functional but incompatible perylene units and a mixture of hexahexyloxytriphenylene matrix doped with 0.1% PBITP10 is homogeneous and liquid crystalline.

U2 - 10.1021/ol103018v

DO - 10.1021/ol103018v

M3 - Article

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