A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid

Filipe A. Almeida Paz; Andrew D. Bond; Y. Z. Khimyak; Jacek Klinowski

doi:10.1107/S0108270102019960

A novel one-dimensional coordination polymer with Cd²⁺ and diethylene-triaminepentaacetic acid

Filipe A. Almeida Paz, Andrew D. Bond, Y. Z. Khimyak, Jacek Klinowski

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

catena-Poly[[[bis[diaqua(4,4′-bipyridine)cadmium(II)]-bis[μ -(N″-carboxymethyldiethylenetriamine-N,N,N′, N″-tetraacetato) cadmium(II)]]-μ-4,4′-bipyridine] tetradecahydrate], [Cd₄(C₁₄H₁₉N₃ O₁₀)₂(C₁₀ H₈N₂)₃ (H₂O)₄]· 14H₂O or [Cd₄(HDTPA)₂(BPY)₃ (H₂O)₄]·14H₂O, where BPY is 4, 4′bipyridine and HDTPA^4- is N″-carboxymethyldiethylenetriamine-N,N,-N′,N″-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand. N,N,N′,N″,N″-diethylenetriaminepentaacetic acid (H₅DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.

Original language	English
Pages (from-to)	m608-m610
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	12
Early online date	26 Nov 2002
DOIs	https://doi.org/10.1107/S0108270102019960
Publication status	Published - Dec 2002
Externally published	Yes

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@article{c835b966675c4249bbdac9c3cdcba867,

title = "A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid",

abstract = "catena-Poly[[[bis[diaqua(4,4′-bipyridine)cadmium(II)]-bis[μ -(N″-carboxymethyldiethylenetriamine-N,N,N′, N″-tetraacetato) cadmium(II)]]-μ-4,4′-bipyridine] tetradecahydrate], [Cd4(C14H19N3 O10)2(C10 H8N2)3 (H2O)4]· 14H2O or [Cd4(HDTPA)2(BPY)3 (H2O)4]·14H2O, where BPY is 4, 4′bipyridine and HDTPA4- is N″-carboxymethyldiethylenetriamine-N,N,-N′,N″-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand. N,N,N′,N″,N″-diethylenetriaminepentaacetic acid (H5DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.",

author = "{Almeida Paz}, {Filipe A.} and Bond, {Andrew D.} and Khimyak, {Y. Z.} and Jacek Klinowski",

year = "2002",

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language = "English",

volume = "58",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid

AU - Almeida Paz, Filipe A.

AU - Bond, Andrew D.

AU - Khimyak, Y. Z.

AU - Klinowski, Jacek

PY - 2002/12

Y1 - 2002/12

N2 - catena-Poly[[[bis[diaqua(4,4′-bipyridine)cadmium(II)]-bis[μ -(N″-carboxymethyldiethylenetriamine-N,N,N′, N″-tetraacetato) cadmium(II)]]-μ-4,4′-bipyridine] tetradecahydrate], [Cd4(C14H19N3 O10)2(C10 H8N2)3 (H2O)4]· 14H2O or [Cd4(HDTPA)2(BPY)3 (H2O)4]·14H2O, where BPY is 4, 4′bipyridine and HDTPA4- is N″-carboxymethyldiethylenetriamine-N,N,-N′,N″-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand. N,N,N′,N″,N″-diethylenetriaminepentaacetic acid (H5DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.

AB - catena-Poly[[[bis[diaqua(4,4′-bipyridine)cadmium(II)]-bis[μ -(N″-carboxymethyldiethylenetriamine-N,N,N′, N″-tetraacetato) cadmium(II)]]-μ-4,4′-bipyridine] tetradecahydrate], [Cd4(C14H19N3 O10)2(C10 H8N2)3 (H2O)4]· 14H2O or [Cd4(HDTPA)2(BPY)3 (H2O)4]·14H2O, where BPY is 4, 4′bipyridine and HDTPA4- is N″-carboxymethyldiethylenetriamine-N,N,-N′,N″-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand. N,N,N′,N″,N″-diethylenetriaminepentaacetic acid (H5DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.

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DO - 10.1107/S0108270102019960

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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ER -

A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid

Abstract

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A novel one-dimensional coordination polymer with Cd²⁺ and diethylene-triaminepentaacetic acid