TY - JOUR
T1 - A passive air sampler for characterizing the vertical concentration profile of gaseous phase polycyclic aromatic hydrocarbons in near soil surface air
AU - Zhang, Yuzhong
AU - Deng, Shuxing
AU - Liu, Yanan
AU - Shen, Guofeng
AU - Li, Xiqing
AU - Cao, Jun
AU - Wang, Xilong
AU - Reid, Brian
AU - Tao, Shu
PY - 2011
Y1 - 2011
N2 - Air–soil exchange is an important process governing the fate of polycyclic aromatic hydrocarbons (PAHs). A novel passive air sampler was designed and tested for measuring the vertical concentration profile of 4 low molecular weight PAHs in gaseous phase (PAHLMW4) in near soil surface air. Air at various heights from 5 to 520 mm above the ground was sampled by polyurethane foam disks held in down-faced cartridges. The samplers were tested at three sites: A: an extremely contaminated site, B: a site near A, and C: a background site on a university campus. Vertical concentration gradients were revealed for PAHLMW4 within a thin layer close to soil surface at the three sites. PAH concentrations either decreased (Site A) or increased (Sites B and C) with height, suggesting either deposition to or evaporation from soils. The sampler is a useful tool for investigating air–soil exchange of gaseous phase semi-volatile organic chemicals.
AB - Air–soil exchange is an important process governing the fate of polycyclic aromatic hydrocarbons (PAHs). A novel passive air sampler was designed and tested for measuring the vertical concentration profile of 4 low molecular weight PAHs in gaseous phase (PAHLMW4) in near soil surface air. Air at various heights from 5 to 520 mm above the ground was sampled by polyurethane foam disks held in down-faced cartridges. The samplers were tested at three sites: A: an extremely contaminated site, B: a site near A, and C: a background site on a university campus. Vertical concentration gradients were revealed for PAHLMW4 within a thin layer close to soil surface at the three sites. PAH concentrations either decreased (Site A) or increased (Sites B and C) with height, suggesting either deposition to or evaporation from soils. The sampler is a useful tool for investigating air–soil exchange of gaseous phase semi-volatile organic chemicals.
U2 - 10.1016/j.envpol.2010.12.002
DO - 10.1016/j.envpol.2010.12.002
M3 - Article
VL - 159
SP - 694
EP - 699
JO - Environmental Pollution
JF - Environmental Pollution
SN - 0269-7491
IS - 3
ER -