TY - JOUR
T1 - A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes
AU - Roşca, Dragoş-Adrian
AU - Smith, Dan A.
AU - Hughes, David L.
AU - Bochmann, Manfred
PY - 2012/10/15
Y1 - 2012/10/15
N2 - The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.
AB - The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.
U2 - 10.1002/anie.201206468
DO - 10.1002/anie.201206468
M3 - Article
VL - 51
SP - 10643
EP - 10646
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 42
ER -