TY - JOUR
T1 - A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis
AU - Fateeva, Alexandra
AU - Chater, Philip A.
AU - Ireland, Christopher P.
AU - Tahir, Asif A.
AU - Khimyak, Yaroslav Z.
AU - Wiper, Paul V.
AU - Darwent, James R.
AU - Rosseinsky, Matthew J.
PY - 2012/7/23
Y1 - 2012/7/23
N2 - Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.
AB - Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.
KW - heterogeneous catalysis
KW - hydrogen production
KW - metal-organic frameworks
KW - porphyrinoids
UR - http://www.scopus.com/inward/record.url?scp=84864215591&partnerID=8YFLogxK
U2 - 10.1002/anie.201202471
DO - 10.1002/anie.201202471
M3 - Article
AN - SCOPUS:84864215591
VL - 51
SP - 7440
EP - 7444
JO - Angewandte Chemie-International Edition
JF - Angewandte Chemie-International Edition
SN - 1433-7851
IS - 30
ER -
