A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

Alexandra Fateeva; Philip A. Chater; Christopher P. Ireland; Asif A. Tahir; Yaroslav Z. Khimyak; Paul V. Wiper; James R. Darwent; Matthew J. Rosseinsky

doi:10.1002/anie.201202471

A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

Alexandra Fateeva
, Philip A. Chater
, Christopher P. Ireland
, Asif A. Tahir
, Yaroslav Z. Khimyak
, Paul V. Wiper
, James R. Darwent
, Matthew J. Rosseinsky

Research output: Contribution to journal › Article › peer-review

784 Citations (Scopus)

Abstract

Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.

Original language	English
Pages (from-to)	7440-7444
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	30
Early online date	13 Jun 2012
DOIs	https://doi.org/10.1002/anie.201202471
Publication status	Published - 23 Jul 2012
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

heterogeneous catalysis
hydrogen production
metal-organic frameworks
porphyrinoids

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10.1002/anie.201202471

Cite this

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title = "A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis",

abstract = "Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.",

keywords = "heterogeneous catalysis, hydrogen production, metal-organic frameworks, porphyrinoids",

author = "Alexandra Fateeva and Chater, \{Philip A.\} and Ireland, \{Christopher P.\} and Tahir, \{Asif A.\} and Khimyak, \{Yaroslav Z.\} and Wiper, \{Paul V.\} and Darwent, \{James R.\} and Rosseinsky, \{Matthew J.\}",

year = "2012",

month = jul,

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doi = "10.1002/anie.201202471",

language = "English",

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pages = "7440--7444",

journal = "Angewandte Chemie - International Edition",

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T1 - A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

AU - Fateeva, Alexandra

AU - Chater, Philip A.

AU - Ireland, Christopher P.

AU - Tahir, Asif A.

AU - Khimyak, Yaroslav Z.

AU - Wiper, Paul V.

AU - Darwent, James R.

AU - Rosseinsky, Matthew J.

PY - 2012/7/23

Y1 - 2012/7/23

N2 - Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.

AB - Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.

KW - heterogeneous catalysis

KW - hydrogen production

KW - metal-organic frameworks

KW - porphyrinoids

UR - https://www.scopus.com/pages/publications/84864215591

U2 - 10.1002/anie.201202471

DO - 10.1002/anie.201202471

M3 - Article

AN - SCOPUS:84864215591

SN - 1433-7851

VL - 51

SP - 7440

EP - 7444

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 30

ER -

A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

Abstract

UN SDGs

Keywords

Access to Document

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