Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile

Mark R. J. Elsegood; Carl Redshaw

doi:10.1002/chem.200800183

Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile

Mark R. J. Elsegood, Carl Redshaw

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The 18th hole: Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me₂NNH₂ and R/R'Zn (R=R'=C₆F₅; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.

Original language	English
Pages (from-to)	3530-3534
Number of pages	5
Journal	Chemistry - A European Journal
Volume	14
Issue number	12
DOIs	https://doi.org/10.1002/chem.200800183
Publication status	Published - 18 Apr 2008

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10.1002/chem.200800183

Cite this

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title = "Alkylzinc hydrazides: Self-assembly of hexanuclear ring systems in acetonitrile",

abstract = "The 18th hole: Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me2NNH2 and R/R'Zn (R=R'=C6F5; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.",

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AU - Redshaw, Carl

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N2 - The 18th hole: Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me2NNH2 and R/R'Zn (R=R'=C6F5; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.

AB - The 18th hole: Novel 18-membered zinc–nitrogen ring systems are readily accessible from the reaction of Me2NNH2 and R/R'Zn (R=R'=C6F5; R=R'=Ph; R=Et, R'=Cl) and subsequent work-up with acetonitrile. More forcing conditions are required in the case of R=R'=Et. The intriguing solid-state structures have been identified by X-ray crystallography using synchrotron radiation (see scheme), and these new complexes undergo hydrolysis to give acetamide hydrazones.

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