Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles

Hiroshi Nomura, Christopher J. Richards

Research output: Contribution to journalArticlepeer-review

78 Citations (Scopus)

Abstract

The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.
Original languageEnglish
Pages (from-to)1726-1740
Number of pages15
JournalChemistry - An Asian Journal
Volume5
Issue number8
Early online date9 Jul 2010
DOIs
Publication statusPublished - 2 Aug 2010

Keywords

  • allylic compounds
  • asymmetric catalysis
  • metallocenes
  • palladacycles
  • planar compounds

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