Allylic imidate rearrangements catalyzed by planar chiral palladacycles

Hiroshi Nomura; Christopher J. Richards

doi:10.1002/asia.201000131

Allylic imidate rearrangements catalyzed by planar chiral palladacycles

Hiroshi Nomura
, Christopher J. Richards

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

Original language	English
Pages (from-to)	1726-1740
Number of pages	15
Journal	Chemistry - An Asian Journal
Volume	5
Issue number	8
Early online date	9 Jul 2010
DOIs	https://doi.org/10.1002/asia.201000131
Publication status	Published - 2 Aug 2010

Keywords

allylic compounds
asymmetric catalysis
metallocenes
palladacycles
planar compounds

Access to Document

10.1002/asia.201000131

Cite this

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title = "Allylic imidate rearrangements catalyzed by planar chiral palladacycles",

abstract = "The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.",

keywords = "allylic compounds, asymmetric catalysis, metallocenes, palladacycles, planar compounds",

author = "Hiroshi Nomura and Richards, \{Christopher J.\}",

year = "2010",

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AU - Nomura, Hiroshi

AU - Richards, Christopher J.

PY - 2010/8/2

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N2 - The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

AB - The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

KW - allylic compounds

KW - asymmetric catalysis

KW - metallocenes

KW - palladacycles

KW - planar compounds

U2 - 10.1002/asia.201000131

DO - 10.1002/asia.201000131

M3 - Article

SN - 1861-4728

VL - 5

SP - 1726

EP - 1740

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 8

ER -