An attenuated total reflectance optrode sensor incorporating infrared-active carbonylmetal probe groups

C. S. Creaser; W. E. Hutchinson; G. R. Stephenson

doi:10.1016/S0925-4005(01)01000-0

An attenuated total reflectance optrode sensor incorporating infrared-active carbonylmetal probe groups

C. S. Creaser, W. E. Hutchinson, G. R. Stephenson

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

An optrode sensor has been constructed by coating fumed silica particles incorporating covalently attached organoironcarbonyl probe groups onto a ZnSe attenuated total reflectance (ATR) element, The sensor may be interrogated remotely using Fourier transform infrared (FTIR) spectroscopy by coupling IR transparent optical fibres to the ATR element. The organometallic probe groups act as components of a sensing system in which analyte/sensor interactions are transduced through shifts in the sharp v(CO) bands of the metal carbonyl reporting group. The potential of the device is demonstrated for pH sensing in the range 7-13 and as a sensor of solvent environment. Coating two different immobilised probe groups onto the ATR element, combined with FTIR measurement, allows the optrode to be used for the independent, multi-component sensing of two analytes. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	150-157
Number of pages	8
Journal	Sensors and Actuators B: Chemical
Volume	82
Issue number	2-3
DOIs	https://doi.org/10.1016/S0925-4005(01)01000-0
Publication status	Published - 28 Feb 2002

Access to Document

10.1016/S0925-4005(01)01000-0

Cite this

@article{8745f4d077634a0eb0659278b3660d24,

title = "An attenuated total reflectance optrode sensor incorporating infrared-active carbonylmetal probe groups",

abstract = "An optrode sensor has been constructed by coating fumed silica particles incorporating covalently attached organoironcarbonyl probe groups onto a ZnSe attenuated total reflectance (ATR) element, The sensor may be interrogated remotely using Fourier transform infrared (FTIR) spectroscopy by coupling IR transparent optical fibres to the ATR element. The organometallic probe groups act as components of a sensing system in which analyte/sensor interactions are transduced through shifts in the sharp v(CO) bands of the metal carbonyl reporting group. The potential of the device is demonstrated for pH sensing in the range 7-13 and as a sensor of solvent environment. Coating two different immobilised probe groups onto the ATR element, combined with FTIR measurement, allows the optrode to be used for the independent, multi-component sensing of two analytes. (C) 2002 Elsevier Science B.V. All rights reserved.",

author = "Creaser, {C. S.} and Hutchinson, {W. E.} and Stephenson, {G. R.}",

year = "2002",

month = feb,

day = "28",

doi = "10.1016/S0925-4005(01)01000-0",

language = "English",

volume = "82",

pages = "150--157",

journal = "Sensors and Actuators B: Chemical",

issn = "0925-4005",

publisher = "Elsevier",

number = "2-3",

}

TY - JOUR

T1 - An attenuated total reflectance optrode sensor incorporating infrared-active carbonylmetal probe groups

AU - Creaser, C. S.

AU - Hutchinson, W. E.

AU - Stephenson, G. R.

PY - 2002/2/28

Y1 - 2002/2/28

N2 - An optrode sensor has been constructed by coating fumed silica particles incorporating covalently attached organoironcarbonyl probe groups onto a ZnSe attenuated total reflectance (ATR) element, The sensor may be interrogated remotely using Fourier transform infrared (FTIR) spectroscopy by coupling IR transparent optical fibres to the ATR element. The organometallic probe groups act as components of a sensing system in which analyte/sensor interactions are transduced through shifts in the sharp v(CO) bands of the metal carbonyl reporting group. The potential of the device is demonstrated for pH sensing in the range 7-13 and as a sensor of solvent environment. Coating two different immobilised probe groups onto the ATR element, combined with FTIR measurement, allows the optrode to be used for the independent, multi-component sensing of two analytes. (C) 2002 Elsevier Science B.V. All rights reserved.

AB - An optrode sensor has been constructed by coating fumed silica particles incorporating covalently attached organoironcarbonyl probe groups onto a ZnSe attenuated total reflectance (ATR) element, The sensor may be interrogated remotely using Fourier transform infrared (FTIR) spectroscopy by coupling IR transparent optical fibres to the ATR element. The organometallic probe groups act as components of a sensing system in which analyte/sensor interactions are transduced through shifts in the sharp v(CO) bands of the metal carbonyl reporting group. The potential of the device is demonstrated for pH sensing in the range 7-13 and as a sensor of solvent environment. Coating two different immobilised probe groups onto the ATR element, combined with FTIR measurement, allows the optrode to be used for the independent, multi-component sensing of two analytes. (C) 2002 Elsevier Science B.V. All rights reserved.

U2 - 10.1016/S0925-4005(01)01000-0

DO - 10.1016/S0925-4005(01)01000-0

M3 - Article

VL - 82

SP - 150

EP - 157

JO - Sensors and Actuators B: Chemical

JF - Sensors and Actuators B: Chemical

SN - 0925-4005

IS - 2-3

ER -