TY - JOUR
T1 - An investigation into the diastereoselective palladation of oxazoline appended cobalt metallocenes
AU - Yeamine, Mehbuba R.
AU - Richards, Christopher J.
N1 - Yeamine, Mehbuba R. Richards, Christopher J.
PY - 2007
Y1 - 2007
N2 - The diastereoselective reactions of palladium acetate with (eta(5)-(S)-2-(4-methylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetraph enylcyclobutadiene)cobalt, which gives a planar chiral palladacycle with (R-p) configuration, and (eta(5)-(S)-2-(4-dimethylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetra phenylcyclobtttadiene)cobalt, which results in the opposite (S-p) configuration, are shown to be a consequence of these reactions displaying thermodynamic and kinetic control, respectively. (c) 2007 Elsevier Ltd. All rights reserved.
AB - The diastereoselective reactions of palladium acetate with (eta(5)-(S)-2-(4-methylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetraph enylcyclobutadiene)cobalt, which gives a planar chiral palladacycle with (R-p) configuration, and (eta(5)-(S)-2-(4-dimethylethyl)oxzazolinylcyclopentadienyl)(eta(4)-tetra phenylcyclobtttadiene)cobalt, which results in the opposite (S-p) configuration, are shown to be a consequence of these reactions displaying thermodynamic and kinetic control, respectively. (c) 2007 Elsevier Ltd. All rights reserved.
U2 - 10.1016/j.tetasy.2007.10.028
DO - 10.1016/j.tetasy.2007.10.028
M3 - Article
VL - 18
SP - 2613
EP - 2616
JO - Tetrahedron: Asymmetry
JF - Tetrahedron: Asymmetry
SN - 0957-4166
IS - 22
ER -