Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate

Luca Rocchigiani; Julio Fernandez Cestau; Peter Budzelaar; Manfred Bochmann

doi:10.1039/C7CC01628J

Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate

Luca Rocchigiani
, Julio Fernandez Cestau
, Peter Budzelaar
, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

6 Downloads (Pure)

Abstract

Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation.

Original language	English
Pages (from-to)	4358-4361
Journal	Chemical Communications
Volume	53
Issue number	31
Early online date	3 Apr 2017
DOIs	https://doi.org/10.1039/C7CC01628J
Publication status	Published - 21 Apr 2017

Access to Document

10.1039/C7CC01628JLicence: CC BY

Accepted manuscriptAccepted author manuscript, 4.21 MB

Cite this

@article{d54d45d9480741fc8a4372161bfcbc73,

title = "Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate",

abstract = "Selective Au-C bond cleavage and arene-C-H activation in (C\textasciicircum{}N\textasciicircum{}C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation. ",

author = "Luca Rocchigiani and \{Fernandez Cestau\}, Julio and Peter Budzelaar and Manfred Bochmann",

year = "2017",

month = apr,

day = "21",

doi = "10.1039/C7CC01628J",

language = "English",

volume = "53",

pages = "4358--4361",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate

AU - Rocchigiani, Luca

AU - Fernandez Cestau, Julio

AU - Budzelaar, Peter

AU - Bochmann, Manfred

PY - 2017/4/21

Y1 - 2017/4/21

N2 - Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation.

AB - Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation.

U2 - 10.1039/C7CC01628J

DO - 10.1039/C7CC01628J

M3 - Article

SN - 1359-7345

VL - 53

SP - 4358

EP - 4361

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -