Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Saad Ibrahim, Pei Meng Woi, Yatimah Alias, Christopher Pickett

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)


We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.
Original languageEnglish
Pages (from-to)8189-8191
Number of pages3
JournalChemical Communications
Issue number43
Publication statusPublished - 2010

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