Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Saad Ibrahim; Pei Meng Woi; Yatimah Alias; Christopher Pickett

doi:10.1039/c0cc02962a

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Saad Ibrahim, Pei Meng Woi, Yatimah Alias, Christopher Pickett

School of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

We show that a redox active {Fe₄S₄}²⁺–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Original language	English
Pages (from-to)	8189-8191
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	43
DOIs	https://doi.org/10.1039/c0cc02962a
Publication status	Published - 2010

Access to Document

10.1039/c0cc02962a

Cite this

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abstract = "We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.",

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AU - Pickett, Christopher

PY - 2010

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AB - We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

U2 - 10.1039/c0cc02962a

DO - 10.1039/c0cc02962a

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