Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Saad Ibrahim; Pei Meng Woi; Yatimah Alias; Christopher Pickett

doi:10.1039/c0cc02962a

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Saad Ibrahim, Pei Meng Woi, Yatimah Alias, Christopher Pickett

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

We show that a redox active {Fe₄S₄}²⁺–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Original language	English
Pages (from-to)	8189-8191
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	43
DOIs	https://doi.org/10.1039/c0cc02962a
Publication status	Published - 2010

Access to Document

10.1039/c0cc02962a

Cite this

@article{ada271a39f69478793dd852f446ad4d2,

title = "Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix",

abstract = "We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.",

author = "Saad Ibrahim and Woi, {Pei Meng} and Yatimah Alias and Christopher Pickett",

year = "2010",

doi = "10.1039/c0cc02962a",

language = "English",

volume = "46",

pages = "8189--8191",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

AU - Ibrahim, Saad

AU - Woi, Pei Meng

AU - Alias, Yatimah

AU - Pickett, Christopher

PY - 2010

Y1 - 2010

N2 - We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

AB - We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

U2 - 10.1039/c0cc02962a

DO - 10.1039/c0cc02962a

M3 - Article

SN - 1364-548X

VL - 46

SP - 8189

EP - 8191

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -