Aryl trihydroxyborates: Easily isolated discrete species convenient for direct application in coupling reactions

Andrew N. Cammidge, Victoria H. M. Goddard, Hermant Gopee, Nicola L. Harrison, David L. Hughes, Christopher J. Schubert, Benjamin M. Sutton, Gary L. Watts, Andrew J. Whitehead

Research output: Contribution to journalArticlepeer-review

99 Citations (Scopus)

Abstract

A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry.
Original languageEnglish
Pages (from-to)4071-4074
Number of pages4
JournalOrganic Letters
Volume8
Issue number18
DOIs
Publication statusPublished - 2006

Cite this