Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH)

Abdessamad Arbaoui; Carl Redshaw; David L. Hughes; Mark R. J. Elsegood

doi:10.1016/j.ica.2008.04.050

Arylboron complexes of the acids Ph₂C(XH)CO₂H (X = O, NH)

Abdessamad Arbaoui, Carl Redshaw, David L. Hughes, Mark R. J. Elsegood

School of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The acids Ph₂C(XH)CO₂H (X = O, NH) readily react with the triarylboron reagents BAr₃ (Ar = Ph, C₆F₅) to form the complexes [Ph₂C(O)CO₂BPh] and [Ph₂C(NH₂)CO₂BPh₂], Ph₂C(p-CH₃C₆H₄)CO₂H [in the presence of Et₃N the complex HNEt₃[Ph₂C(OH)CO₂B(C₆F₅)₃] (3b) was formed], and [Ph₂C(NH₃)CO₂B(C₆F₅)₃], respectively.

Original language	English
Pages (from-to)	509-514
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	362
Issue number	2
DOIs	https://doi.org/10.1016/j.ica.2008.04.050
Publication status	Published - 2009

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10.1016/j.ica.2008.04.050

Cite this

@article{45dbec9a726947fd997105f022e0d362,

title = "Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH)",

abstract = "The acids Ph2C(XH)CO2H (X = O, NH) readily react with the triarylboron reagents BAr3 (Ar = Ph, C6F5) to form the complexes [Ph2C(O)CO2BPh] and [Ph2C(NH2)CO2BPh2], Ph2C(p-CH3C6H4)CO2H [in the presence of Et3N the complex HNEt3[Ph2C(OH)CO2B(C6F5)3] (3b) was formed], and [Ph2C(NH3)CO2B(C6F5)3], respectively.",

author = "Abdessamad Arbaoui and Carl Redshaw and Hughes, {David L.} and Elsegood, {Mark R. J.}",

year = "2009",

doi = "10.1016/j.ica.2008.04.050",

language = "English",

volume = "362",

pages = "509--514",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Arylboron complexes of the acids Ph2C(XH)CO2H (X = O, NH)

AU - Arbaoui, Abdessamad

AU - Redshaw, Carl

AU - Hughes, David L.

AU - Elsegood, Mark R. J.

PY - 2009

Y1 - 2009

N2 - The acids Ph2C(XH)CO2H (X = O, NH) readily react with the triarylboron reagents BAr3 (Ar = Ph, C6F5) to form the complexes [Ph2C(O)CO2BPh] and [Ph2C(NH2)CO2BPh2], Ph2C(p-CH3C6H4)CO2H [in the presence of Et3N the complex HNEt3[Ph2C(OH)CO2B(C6F5)3] (3b) was formed], and [Ph2C(NH3)CO2B(C6F5)3], respectively.

AB - The acids Ph2C(XH)CO2H (X = O, NH) readily react with the triarylboron reagents BAr3 (Ar = Ph, C6F5) to form the complexes [Ph2C(O)CO2BPh] and [Ph2C(NH2)CO2BPh2], Ph2C(p-CH3C6H4)CO2H [in the presence of Et3N the complex HNEt3[Ph2C(OH)CO2B(C6F5)3] (3b) was formed], and [Ph2C(NH3)CO2B(C6F5)3], respectively.

U2 - 10.1016/j.ica.2008.04.050

DO - 10.1016/j.ica.2008.04.050

M3 - Article

VL - 362

SP - 509

EP - 514

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 2

ER -