Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Shaun Garratt; Antonio Guerrero; David L. Hughes; Manfred Bochmann

doi:10.1002/anie.200353787

Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Shaun Garratt, Antonio Guerrero, David L. Hughes, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The initiator system [Zn(C₆F₅)₂]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

Original language	English
Pages (from-to)	2166-2169
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	43
Issue number	16
DOIs	https://doi.org/10.1002/anie.200353787
Publication status	Published - 15 Mar 2004

Access to Document

10.1002/anie.200353787

Cite this

@article{0525c2f136f34fb182909c5b9d252733,

title = "Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content",

abstract = "The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.",

author = "Shaun Garratt and Antonio Guerrero and Hughes, {David L.} and Manfred Bochmann",

year = "2004",

month = mar,

day = "15",

doi = "10.1002/anie.200353787",

language = "English",

volume = "43",

pages = "2166--2169",

journal = "Angewandte Chemie-International Edition",

issn = "1433-7851",

publisher = "Wiley",

number = "16",

}

TY - JOUR

T1 - Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

AU - Garratt, Shaun

AU - Guerrero, Antonio

AU - Hughes, David L.

AU - Bochmann, Manfred

PY - 2004/3/15

Y1 - 2004/3/15

N2 - The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

AB - The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

U2 - 10.1002/anie.200353787

DO - 10.1002/anie.200353787

M3 - Article

VL - 43

SP - 2166

EP - 2169

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

SN - 1433-7851

IS - 16

ER -