Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Shaun Garratt; Antonio Guerrero; David L. Hughes; Manfred Bochmann

doi:10.1002/anie.200353787

Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Shaun Garratt
, Antonio Guerrero
, David L. Hughes
, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The initiator system [Zn(C₆F₅)₂]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

Original language	English
Pages (from-to)	2166-2169
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	43
Issue number	16
DOIs	https://doi.org/10.1002/anie.200353787
Publication status	Published - 15 Mar 2004

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10.1002/anie.200353787

Cite this

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title = "Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content",

abstract = "The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.",

author = "Shaun Garratt and Antonio Guerrero and Hughes, \{David L.\} and Manfred Bochmann",

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AU - Garratt, Shaun

AU - Guerrero, Antonio

AU - Hughes, David L.

AU - Bochmann, Manfred

PY - 2004/3/15

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N2 - The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

AB - The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

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DO - 10.1002/anie.200353787

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JF - Angewandte Chemie International Edition

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