B(C6F5)3 as aC6F5 transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr2Cp″2(C6F5)2{μ-η5∶η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3}]

Timothy J. Woodman; Mark Thornton-Pett; Manfred Bochmann

doi:10.1039/b009016f

B(C₆F₅)₃ as aC₆F₅ transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr₂Cp″₂(C₆F₅)₂{μ-η⁵∶η⁵-C₄H₄BCH₂-η³,κF-CHCHCHB(C₆F₅)₃}]

Timothy J. Woodman
, Mark Thornton-Pett
, Manfred Bochmann

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Warming mixtures of (Cp^R)Zr(?³-C₄H₇)(? ⁴-C₄H₆) and B(C₆F₅)₃ leads to complete transfer of all three C₆F₅ substituents of a B(C₆F₅)₃ molecule to give borole-bridged triple-decker complexes with a Zr₂C₄B core, a zwitterionic structure and an unusually strong Zr–F donor interaction.

Original language	English
Pages (from-to)	329-330
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/b009016f
Publication status	Published - 1 Feb 2001

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10.1039/b009016f

Cite this

@article{4f84756acb754530881ffcf93ee8efb8,

title = "B(C6F5)3 as aC6F5 transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr2Cp″2(C6F5)2\{μ-η5∶η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3\}]",

abstract = "Warming mixtures of (CpR)Zr(?3-C4H7)(? 4-C4H6) and B(C6F5)3 leads to complete transfer of all three C6F5 substituents of a B(C6F5)3 molecule to give borole-bridged triple-decker complexes with a Zr2C4B core, a zwitterionic structure and an unusually strong Zr–F donor interaction.",

author = "Woodman, \{Timothy J.\} and Mark Thornton-Pett and Manfred Bochmann",

year = "2001",

month = feb,

day = "1",

doi = "10.1039/b009016f",

language = "English",

pages = "329--330",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "4",

}

B(C₆F₅)₃ as aC₆F₅ transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr₂Cp″₂(C₆F₅)₂{μ-η⁵∶η⁵-C₄H₄BCH₂-η³,κF-CHCHCHB(C₆F₅)₃}]. / Woodman, Timothy J.; Thornton-Pett, Mark; Bochmann, Manfred.
In: Chemical Communications, No. 4, 01.02.2001, p. 329-330.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - B(C6F5)3 as aC6F5 transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr2Cp″2(C6F5)2{μ-η5∶η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3}]

AU - Woodman, Timothy J.

AU - Thornton-Pett, Mark

AU - Bochmann, Manfred

PY - 2001/2/1

Y1 - 2001/2/1

N2 - Warming mixtures of (CpR)Zr(?3-C4H7)(? 4-C4H6) and B(C6F5)3 leads to complete transfer of all three C6F5 substituents of a B(C6F5)3 molecule to give borole-bridged triple-decker complexes with a Zr2C4B core, a zwitterionic structure and an unusually strong Zr–F donor interaction.

AB - Warming mixtures of (CpR)Zr(?3-C4H7)(? 4-C4H6) and B(C6F5)3 leads to complete transfer of all three C6F5 substituents of a B(C6F5)3 molecule to give borole-bridged triple-decker complexes with a Zr2C4B core, a zwitterionic structure and an unusually strong Zr–F donor interaction.

U2 - 10.1039/b009016f

DO - 10.1039/b009016f

M3 - Article

SN - 1364-548X

SP - 329

EP - 330

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -