TY - JOUR
T1 - Bis(4,4′-bipyridine)tetraaquacobalt(II) 2,6-naphathalenedicarboxylate dihydrate
AU - Almeida Paz, Filipe A.
AU - Khimyak, Yaroslav Z.
AU - Klinowski, Jacek
PY - 2003/1
Y1 - 2003/1
N2 - The title compound, [Co(C10H8N2) 2(H2O)4](C12H6O 4)·2H2O (where C10H8N 2 is 4,4′-bipyridine, BPY, and C12H 6O4 is 2,6-naphthalenedicarboxylate, NDC2-), (CUmof-6), was synthesized under mild hydrothermal conditions. The structure contains [Co(BPY)2(H2O)4]2+ complex cations, which stack along the a axis through close face-to-face contacts. Uncoordinated NDC2- anions are strongly hydrogen bonded to the complex cations. The Co2+ cation and the centre of gravity of NDC2- are located on crystallographic centres of symmetry.
AB - The title compound, [Co(C10H8N2) 2(H2O)4](C12H6O 4)·2H2O (where C10H8N 2 is 4,4′-bipyridine, BPY, and C12H 6O4 is 2,6-naphthalenedicarboxylate, NDC2-), (CUmof-6), was synthesized under mild hydrothermal conditions. The structure contains [Co(BPY)2(H2O)4]2+ complex cations, which stack along the a axis through close face-to-face contacts. Uncoordinated NDC2- anions are strongly hydrogen bonded to the complex cations. The Co2+ cation and the centre of gravity of NDC2- are located on crystallographic centres of symmetry.
UR - http://www.scopus.com/inward/record.url?scp=18444410277&partnerID=8YFLogxK
U2 - 10.1107/S1600536802022122
DO - 10.1107/S1600536802022122
M3 - Article
AN - SCOPUS:18444410277
VL - 59
SP - m8-m10
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 1
ER -