TY - JOUR
T1 - Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation
AU - Redshaw, Carl
AU - Zhan, Shu-Zhong
AU - Dale, Sophie H.
AU - Elsegood, Mark R. J.
PY - 2008/3/25
Y1 - 2008/3/25
N2 - The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.
AB - The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.
U2 - 10.1016/j.inoche.2008.03.020
DO - 10.1016/j.inoche.2008.03.020
M3 - Article
VL - 11
SP - 754
EP - 756
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 7
ER -