Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation

Carl Redshaw; Shu-Zhong Zhan; Sophie H. Dale; Mark R. J. Elsegood

doi:10.1016/j.inoche.2008.03.020

Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation

Carl Redshaw, Shu-Zhong Zhan, Sophie H. Dale, Mark R. J. Elsegood

School of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH₃) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH₃) led, on reaction with [Re(t-BuN)₃(OSiMe₃)], to the isolation of the complexes [Re(t-BuN)₂(N-capped)] (1) and [Re(OSiMe₃)(t-BuN)₂(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.

Original language	English
Pages (from-to)	754-756
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2008.03.020
Publication status	Published - 25 Mar 2008

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10.1016/j.inoche.2008.03.020

Cite this

@article{ee4845da279c4c53a0424977af5dc555,

title = "Bis(imido) rhenium complexes bearing C- or N-capped {\textquoteleft}tripodal{\textquoteright} ligands: Bi- versus tri-dentate ligation",

abstract = "The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.",

author = "Carl Redshaw and Shu-Zhong Zhan and Dale, {Sophie H.} and Elsegood, {Mark R. J.}",

year = "2008",

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doi = "10.1016/j.inoche.2008.03.020",

language = "English",

volume = "11",

pages = "754--756",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

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TY - JOUR

T1 - Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation

AU - Redshaw, Carl

AU - Zhan, Shu-Zhong

AU - Dale, Sophie H.

AU - Elsegood, Mark R. J.

PY - 2008/3/25

Y1 - 2008/3/25

N2 - The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.

AB - The differing geometrical constraints of the tripodal ligands tris(hydroxyphenyl)amine (N-cappedH3) and tris(3,5-di-t-Bu-2-hydroxyphenyl)methane (C-cappedH3) led, on reaction with [Re(t-BuN)3(OSiMe3)], to the isolation of the complexes [Re(t-BuN)2(N-capped)] (1) and [Re(OSiMe3)(t-BuN)2(C-cappedH)] (2), respectively. Both 1 · 1/2MeCN and 2 have been structurally characterized using X-ray synchrotron radiation.

U2 - 10.1016/j.inoche.2008.03.020

DO - 10.1016/j.inoche.2008.03.020

M3 - Article

VL - 11

SP - 754

EP - 756

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

IS - 7

ER -