Branching out with aminals: microporous organic polymers from difunctional monomers

Andrea Laybourn; Robert Dawson; Rob Clowes; Jonathan A. Iggo; Andrew I. Cooper; Yaroslav Z. Khimyak; Dave J. Adams

doi:10.1039/c2py00506a

Branching out with aminals: microporous organic polymers from difunctional monomers

Andrea Laybourn, Robert Dawson, Rob Clowes, Jonathan A. Iggo, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams

Pharmaceutical Materials and Soft Matter

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500–600 m2 g−1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.

Original language	English
Pages (from-to)	533-537
Number of pages	5
Journal	Polymer Chemistry
Volume	3
Issue number	2
DOIs	https://doi.org/10.1039/c2py00506a
Publication status	Published - 1 Feb 2012

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10.1039/c2py00506a

Cite this

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title = "Branching out with aminals: microporous organic polymers from difunctional monomers",

abstract = "Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500–600 m2 g−1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.",

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AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

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AB - Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500–600 m2 g−1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.

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