Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes

Philip Bulman Page; Yohan Chan; John Liddle; Mark Elsegood

doi:10.1016/j.tet.2014.07.052

Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes

Philip Bulman Page
, Yohan Chan
, John Liddle
, Mark Elsegood

Research output: Contribution to journal › Article › peer-review

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Abstract

A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product epoxides.

Original language	English
Pages (from-to)	7283-7305
Number of pages	23
Journal	Tetrahedron
Volume	70
Issue number	40
DOIs	https://doi.org/10.1016/j.tet.2014.07.052
Publication status	Published - 7 Oct 2014

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10.1016/j.tet.2014.07.052Licence: CC BY

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Cite this

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title = "Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes",

abstract = "A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57\% ee in the product epoxides.",

author = "\{Bulman Page\}, Philip and Yohan Chan and John Liddle and Mark Elsegood",

note = "Open access under a Creative Commons Attribution 4.0 International licence http://creativecommons.org/licenses/by/4.0/.",

year = "2014",

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T1 - Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes

AU - Bulman Page, Philip

AU - Chan, Yohan

AU - Liddle, John

AU - Elsegood, Mark

N1 - Open access under a Creative Commons Attribution 4.0 International licence http://creativecommons.org/licenses/by/4.0/.

PY - 2014/10/7

Y1 - 2014/10/7

N2 - A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product epoxides.

AB - A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product epoxides.

U2 - 10.1016/j.tet.2014.07.052

DO - 10.1016/j.tet.2014.07.052

M3 - Article

SN - 0040-4020

VL - 70

SP - 7283

EP - 7305

JO - Tetrahedron

JF - Tetrahedron

IS - 40

ER -