Cobalt phosphosulfide nanoparticles encapsulated into heteroatom-doped carbon as bifunctional electrocatalyst for Zn−air battery

Xiaolong Xu; Shuo Wang; Shiquan Guo; Kwan San Hui; Jiameng Ma; Duc Anh Dinh; Kwun Nam Hui; Hao Wang; Lipeng Zhang; Guowei Zhou

doi:10.1016/j.apmate.2021.12.003

Cobalt phosphosulfide nanoparticles encapsulated into heteroatom-doped carbon as bifunctional electrocatalyst for Zn−air battery

Xiaolong Xu, Shuo Wang, Shiquan Guo, Kwan San Hui, Jiameng Ma, Duc Anh Dinh, Kwun Nam Hui, Hao Wang, Lipeng Zhang, Guowei Zhou

Research output: Contribution to journal › Article › peer-review

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Abstract

CoPS nanoparticles encapsulated with S, P, N tri-doped carbon material (SPNC) were proposed as bifunctional electrocatalyst of oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) derived from zeolitic imidazolate framework-67. Density functional theory calculations consistently revealed that P element in CoPS@SPNC improves the electrical conductivity and reduces OH∗ hydrogenation energy barrier on Co sites, thereby facilitating the overall ORR/OER activities. A flexible Zn–air battery with CoPS@SPNC delivered an overpotential of 0.49 V, an energy efficiency above 80%, and a discharge voltage of 1.29 V at 2 mA cm−2 for 80 h.

Original language	English
Article number	100027
Journal	Advanced Powder Materials
Volume	1
Issue number	3
Early online date	23 Dec 2021
DOIs	https://doi.org/10.1016/j.apmate.2021.12.003
Publication status	Published - Jul 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Bifunctional electrocatalyst
Heteroatom doping
Zeolitic imidazolate framework
Zn–air battery

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10.1016/j.apmate.2021.12.003Licence: CC BY-NC-ND

Accepted_MnauscriptAccepted author manuscript, 2.06 MBLicence: CC BY-NC-ND

https://linkinghub.elsevier.com/retrieve/pii/S2772834X21000270Licence: CC BY-NC-ND

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title = "Cobalt phosphosulfide nanoparticles encapsulated into heteroatom-doped carbon as bifunctional electrocatalyst for Zn−air battery",

abstract = "CoPS nanoparticles encapsulated with S, P, N tri-doped carbon material (SPNC) were proposed as bifunctional electrocatalyst of oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) derived from zeolitic imidazolate framework-67. Density functional theory calculations consistently revealed that P element in CoPS@SPNC improves the electrical conductivity and reduces OH∗ hydrogenation energy barrier on Co sites, thereby facilitating the overall ORR/OER activities. A flexible Zn–air battery with CoPS@SPNC delivered an overpotential of 0.49 V, an energy efficiency above 80%, and a discharge voltage of 1.29 V at 2 mA cm−2 for 80 h.",

keywords = "Bifunctional electrocatalyst, Heteroatom doping, Zeolitic imidazolate framework, Zn–air battery",

author = "Xiaolong Xu and Shuo Wang and Shiquan Guo and {San Hui}, Kwan and Jiameng Ma and Dinh, {Duc Anh} and Hui, {Kwun Nam} and Hao Wang and Lipeng Zhang and Guowei Zhou",

note = "Funding Information: This work was supported by the funding from Qilu University of Technology (Shandong Academy of Sciences), the Science and Technology Development Fund, Macau SAR (File No. 191/2017/A3, 041/2019/A1, 046/2019/AFJ, 0021/2019/AIR), the National Natural Science Foundation of China (Grant No. 51972180), the Multi-Year Research Grants (Nos. MYRG2017-00216-FST and MYRG2018-00192-IAPME) from the Research Services and Knowledge Transfer Office at the University of Macau, and UEA funding.",

year = "2022",

month = jul,

doi = "10.1016/j.apmate.2021.12.003",

language = "English",

volume = "1",

journal = "Advanced Powder Materials",

issn = "2772-834X",

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TY - JOUR

T1 - Cobalt phosphosulfide nanoparticles encapsulated into heteroatom-doped carbon as bifunctional electrocatalyst for Zn−air battery

AU - Xu, Xiaolong

AU - Wang, Shuo

AU - Guo, Shiquan

AU - San Hui, Kwan

AU - Ma, Jiameng

AU - Dinh, Duc Anh

AU - Hui, Kwun Nam

AU - Wang, Hao

AU - Zhang, Lipeng

AU - Zhou, Guowei

N1 - Funding Information: This work was supported by the funding from Qilu University of Technology (Shandong Academy of Sciences), the Science and Technology Development Fund, Macau SAR (File No. 191/2017/A3, 041/2019/A1, 046/2019/AFJ, 0021/2019/AIR), the National Natural Science Foundation of China (Grant No. 51972180), the Multi-Year Research Grants (Nos. MYRG2017-00216-FST and MYRG2018-00192-IAPME) from the Research Services and Knowledge Transfer Office at the University of Macau, and UEA funding.

PY - 2022/7

Y1 - 2022/7

N2 - CoPS nanoparticles encapsulated with S, P, N tri-doped carbon material (SPNC) were proposed as bifunctional electrocatalyst of oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) derived from zeolitic imidazolate framework-67. Density functional theory calculations consistently revealed that P element in CoPS@SPNC improves the electrical conductivity and reduces OH∗ hydrogenation energy barrier on Co sites, thereby facilitating the overall ORR/OER activities. A flexible Zn–air battery with CoPS@SPNC delivered an overpotential of 0.49 V, an energy efficiency above 80%, and a discharge voltage of 1.29 V at 2 mA cm−2 for 80 h.

AB - CoPS nanoparticles encapsulated with S, P, N tri-doped carbon material (SPNC) were proposed as bifunctional electrocatalyst of oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) derived from zeolitic imidazolate framework-67. Density functional theory calculations consistently revealed that P element in CoPS@SPNC improves the electrical conductivity and reduces OH∗ hydrogenation energy barrier on Co sites, thereby facilitating the overall ORR/OER activities. A flexible Zn–air battery with CoPS@SPNC delivered an overpotential of 0.49 V, an energy efficiency above 80%, and a discharge voltage of 1.29 V at 2 mA cm−2 for 80 h.

KW - Bifunctional electrocatalyst

KW - Heteroatom doping

KW - Zeolitic imidazolate framework

KW - Zn–air battery

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U2 - 10.1016/j.apmate.2021.12.003

DO - 10.1016/j.apmate.2021.12.003

M3 - Article

SN - 2772-834X

VL - 1

JO - Advanced Powder Materials

JF - Advanced Powder Materials

IS - 3

M1 - 100027

ER -

Cobalt phosphosulfide nanoparticles encapsulated into heteroatom-doped carbon as bifunctional electrocatalyst for Zn−air battery

Abstract

UN SDGs

Keywords

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