Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin

Andrew N. Cammidge; Peter J. Scaife; Gûlen Berber; David L. Hughes

doi:10.1021/ol050962g

Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin

Andrew N. Cammidge, Peter J. Scaife, Gûlen Berber, David L. Hughes

Synthetic and Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

[GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.

Original language	English
Pages (from-to)	3413-3416
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	16
DOIs	https://doi.org/10.1021/ol050962g
Publication status	Published - 2005

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10.1021/ol050962g

Cite this

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title = "Cofacial porphyrin-ferrocene dyads and a new class of conjugated porphyrin",

abstract = "[GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.",

author = "Cammidge, {Andrew N.} and Scaife, {Peter J.} and G{\^u}len Berber and Hughes, {David L.}",

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AU - Scaife, Peter J.

AU - Berber, Gûlen

AU - Hughes, David L.

PY - 2005

Y1 - 2005

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AB - [GRAPHIC] A porphyrin-ferrocene dyad has been synthesized in which there is close face-to-face contact between the two aromatic systems, providing a model for heterobimetallic polymers based on the same repeating unit. Attempts to synthesize the 2:1 adduct instead led to a remarkable intramolecular Heck-type cyclization which planarizes the system and extends the conjugation.

U2 - 10.1021/ol050962g

DO - 10.1021/ol050962g

M3 - Article

SN - 1523-7052

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EP - 3416

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -