CONTRA: Improving the performance of dynamic investigations in natural abundance organic solids by mirror-symmetric constant-time CODEX

Detlef Reichert; Ovidiu Pascui; Tito J. Bonagamba; Peter Belton; Asher Schmidt; Eduardo Ribeiro deAzevedo

doi:10.1016/j.jmr.2007.11.003

CONTRA: Improving the performance of dynamic investigations in natural abundance organic solids by mirror-symmetric constant-time CODEX

Detlef Reichert, Ovidiu Pascui, Tito J. Bonagamba, Peter Belton, Asher Schmidt, Eduardo Ribeiro deAzevedo

School of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

We present a minor but essential modification to the CODEX 1D-MAS exchange experiment. The new CONTRA method, which requires minor changes of the original sequence only, has advantages over the previously introduced S-CODEX, since it is less sensitive to artefacts caused by finite pulse lengths. The performance of this variant, including the finite pulse effect, was confirmed by SIMPSON calculations and demonstrated on a number of dynamic systems.

Original language	English
Pages (from-to)	141-147
Number of pages	7
Journal	Journal of Magnetic Resonance
Volume	191
Issue number	1
DOIs	https://doi.org/10.1016/j.jmr.2007.11.003
Publication status	Published - 2008

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10.1016/j.jmr.2007.11.003

Cite this

@article{dd41102c2096408fb09dd869f9da6443,

title = "CONTRA: Improving the performance of dynamic investigations in natural abundance organic solids by mirror-symmetric constant-time CODEX",

abstract = "We present a minor but essential modification to the CODEX 1D-MAS exchange experiment. The new CONTRA method, which requires minor changes of the original sequence only, has advantages over the previously introduced S-CODEX, since it is less sensitive to artefacts caused by finite pulse lengths. The performance of this variant, including the finite pulse effect, was confirmed by SIMPSON calculations and demonstrated on a number of dynamic systems.",

author = "Detlef Reichert and Ovidiu Pascui and Bonagamba, {Tito J.} and Peter Belton and Asher Schmidt and deAzevedo, {Eduardo Ribeiro}",

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volume = "191",

pages = "141--147",

journal = "Journal of Magnetic Resonance",

issn = "0022-2364",

publisher = "Academic Press Inc.",

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CONTRA: Improving the performance of dynamic investigations in natural abundance organic solids by mirror-symmetric constant-time CODEX. / Reichert, Detlef; Pascui, Ovidiu; Bonagamba, Tito J.; Belton, Peter; Schmidt, Asher; deAzevedo, Eduardo Ribeiro.

In: Journal of Magnetic Resonance, Vol. 191, No. 1, 2008, p. 141-147.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - CONTRA: Improving the performance of dynamic investigations in natural abundance organic solids by mirror-symmetric constant-time CODEX

AU - Reichert, Detlef

AU - Pascui, Ovidiu

AU - Bonagamba, Tito J.

AU - Belton, Peter

AU - Schmidt, Asher

AU - deAzevedo, Eduardo Ribeiro

PY - 2008

Y1 - 2008

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AB - We present a minor but essential modification to the CODEX 1D-MAS exchange experiment. The new CONTRA method, which requires minor changes of the original sequence only, has advantages over the previously introduced S-CODEX, since it is less sensitive to artefacts caused by finite pulse lengths. The performance of this variant, including the finite pulse effect, was confirmed by SIMPSON calculations and demonstrated on a number of dynamic systems.

U2 - 10.1016/j.jmr.2007.11.003

DO - 10.1016/j.jmr.2007.11.003

M3 - Article

VL - 191

SP - 141

EP - 147

JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

SN - 0022-2364

IS - 1

ER -