Controlled scrambling in porphyrin synthesis-selective synthesis of 5,10-disubstituted porphyrins

A Cammidge; O. Ozturk

doi:10.1016/S0040-4039(00)01965-1

Controlled scrambling in porphyrin synthesis-selective synthesis of 5,10-disubstituted porphyrins

A Cammidge, O. Ozturk

Research output: Contribution to journal › Article › peer-review

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Abstract

Condensation of phenyldipyrromethane with bisnaphthaldehyde 3 leads to unexpected formation of the scrambled 5,10-bridged porphyrin 5; this unprecedented selectivity suggests that an alternative scrambling mechanism to dipyrromethane acidolysis is operating.

Original language	English
Pages (from-to)	355-358
Number of pages	4
Journal	Tetrahedron Letters
Volume	42
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(00)01965-1
Publication status	Published - 3 Jan 2001

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title = "Controlled scrambling in porphyrin synthesis-selective synthesis of 5,10-disubstituted porphyrins",

abstract = "Condensation of phenyldipyrromethane with bisnaphthaldehyde 3 leads to unexpected formation of the scrambled 5,10-bridged porphyrin 5; this unprecedented selectivity suggests that an alternative scrambling mechanism to dipyrromethane acidolysis is operating.",

author = "A Cammidge and O. Ozturk",

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AU - Cammidge, A

AU - Ozturk, O.

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N2 - Condensation of phenyldipyrromethane with bisnaphthaldehyde 3 leads to unexpected formation of the scrambled 5,10-bridged porphyrin 5; this unprecedented selectivity suggests that an alternative scrambling mechanism to dipyrromethane acidolysis is operating.

AB - Condensation of phenyldipyrromethane with bisnaphthaldehyde 3 leads to unexpected formation of the scrambled 5,10-bridged porphyrin 5; this unprecedented selectivity suggests that an alternative scrambling mechanism to dipyrromethane acidolysis is operating.

U2 - 10.1016/S0040-4039(00)01965-1

DO - 10.1016/S0040-4039(00)01965-1

M3 - Article

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SP - 355

EP - 358

JO - Tetrahedron Letters

JF - Tetrahedron Letters

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