Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

Fenfen Xu; Cédric Tard; Xiufeng Wang; Saad Ibrahim; David Hughes; Wei Zhong; Xirui Zeng; Qiuyan Luo; Xiaoming Liu; Christopher Pickett

doi:10.1039/b712805c

Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

Fenfen Xu
, Cédric Tard
, Xiufeng Wang
, Saad Ibrahim
, David Hughes
, Wei Zhong
, Xirui Zeng
, Qiuyan Luo
, Xiaoming Liu
, Christopher Pickett

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially ‘switched-on’ via a ligand protonation pathway which is competitive with metal-metal bond protonation.

Original language	English
Pages (from-to)	606-608
Number of pages	3
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/b712805c
Publication status	Published - 2008

Access to Document

10.1039/b712805c

Cite this

@article{eb02b8e13e09473aa6181a1e3769b970,

title = "Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site",

abstract = "Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially {\textquoteleft}switched-on{\textquoteright} via a ligand protonation pathway which is competitive with metal-metal bond protonation.",

author = "Fenfen Xu and C{\'e}dric Tard and Xiufeng Wang and Saad Ibrahim and David Hughes and Wei Zhong and Xirui Zeng and Qiuyan Luo and Xiaoming Liu and Christopher Pickett",

year = "2008",

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language = "English",

pages = "606--608",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

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T1 - Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

AU - Xu, Fenfen

AU - Tard, Cédric

AU - Wang, Xiufeng

AU - Ibrahim, Saad

AU - Hughes, David

AU - Zhong, Wei

AU - Zeng, Xirui

AU - Luo, Qiuyan

AU - Liu, Xiaoming

AU - Pickett, Christopher

PY - 2008

Y1 - 2008

N2 - Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially ‘switched-on’ via a ligand protonation pathway which is competitive with metal-metal bond protonation.

AB - Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially ‘switched-on’ via a ligand protonation pathway which is competitive with metal-metal bond protonation.

U2 - 10.1039/b712805c

DO - 10.1039/b712805c

M3 - Article

SN - 1364-548X

SP - 606

EP - 608

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -