Convergent synthesis of a trisaccharide as its 2-(trimethylsilyl)ethyl glycoside related to the flavonoid triglycoside from Gymnema sylvestre

Balaram Mukhopadhyay; Robert A. Field

doi:10.1016/j.carres.2006.03.019

Convergent synthesis of a trisaccharide as its 2-(trimethylsilyl)ethyl glycoside related to the flavonoid triglycoside from Gymnema sylvestre

Balaram Mukhopadhyay, Robert A. Field

School of Chemistry, Pharmacy and Pharmacology

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The glycone part of the flavonoid triglycoside, kaempferol 3-O-β-d-glucopyranosyl-(1→4)-α-l-rhamnopyranosyl-(1→6)-β-d-galactopyranoside, has been synthesized in good yield and stereoselectivity using N-iodosuccinimide and HClO₄-silica promoted glycosylations of thioglycoside donors.

Original language	English
Pages (from-to)	1697-1701
Number of pages	5
Journal	Carbohydrate Research
Volume	341
Issue number	10
DOIs	https://doi.org/10.1016/j.carres.2006.03.019
Publication status	Published - 24 Jul 2006

Keywords

Antidiabetic
Flavonoids
HClO-silica

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10.1016/j.carres.2006.03.019

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abstract = "The glycone part of the flavonoid triglycoside, kaempferol 3-O-β-d-glucopyranosyl-(1→4)-α-l-rhamnopyranosyl-(1→6)-β-d-galactopyranoside, has been synthesized in good yield and stereoselectivity using N-iodosuccinimide and HClO4-silica promoted glycosylations of thioglycoside donors.",

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KW - HClO-silica

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Convergent synthesis of a trisaccharide as its 2-(trimethylsilyl)ethyl glycoside related to the flavonoid triglycoside from Gymnema sylvestre

Abstract

Keywords

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