Derivatized carbon powder electrodes: reagentless pH sensors

Henry C. Leventis; Ian Streeter; Gregory G. Wildgoose; Nathan S. Lawrence; Li Jiang; Timothy G. J. Jones; Richard G. Compton

doi:10.1016/j.talanta.2004.01.017

Derivatized carbon powder electrodes: reagentless pH sensors

Henry C. Leventis, Ian Streeter, Gregory G. Wildgoose, Nathan S. Lawrence, Li Jiang, Timothy G. J. Jones, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

94 Citations (Scopus)

Abstract

The authors derivatize C powder with anthracene, azobenzene, diphenylamine, 9,10-diphenylanthracene, methylene blue, 3-nitrofluoranthene, 6-nitrochrysene, 9-nitroanthracene, 9,10-phenanthraquinone (PAQ), thionin, and fast black K (2,5-dimethoxy-4-[(4-nitrophenyl)azo]benzenediazonium chloride) and sep. immobilize the resulting material onto a bppg electrode. The authors use cyclic voltammetry (CV) to demonstrate that the obsd. voltammetric response for each derivatized C is consistent with that of an immobilized species. Further, the authors use CV and square wave voltammetry (SWV) to study the effect of pH on the peak potentials of each compd. studied over the range pH 1-12 and at elevated temps. up to 70° to demonstrate the versatility of derivatized C electrodes as reagentless pH sensors. [on SciFinder(R)]

Original language	English
Pages (from-to)	1039-1051
Number of pages	13
Journal	Talanta
Volume	63
Early online date	1 Apr 2004
DOIs	https://doi.org/10.1016/j.talanta.2004.01.017
Publication status	Published - 8 Jul 2004

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10.1016/j.talanta.2004.01.017

Cite this

@article{549cc5cab88d47e9b734efd34152b97b,

title = "Derivatized carbon powder electrodes: reagentless pH sensors",

abstract = "The authors derivatize C powder with anthracene, azobenzene, diphenylamine, 9,10-diphenylanthracene, methylene blue, 3-nitrofluoranthene, 6-nitrochrysene, 9-nitroanthracene, 9,10-phenanthraquinone (PAQ), thionin, and fast black K (2,5-dimethoxy-4-[(4-nitrophenyl)azo]benzenediazonium chloride) and sep. immobilize the resulting material onto a bppg electrode. The authors use cyclic voltammetry (CV) to demonstrate that the obsd. voltammetric response for each derivatized C is consistent with that of an immobilized species. Further, the authors use CV and square wave voltammetry (SWV) to study the effect of pH on the peak potentials of each compd. studied over the range pH 1-12 and at elevated temps. up to 70° to demonstrate the versatility of derivatized C electrodes as reagentless pH sensors. [on SciFinder(R)]",

author = "Leventis, {Henry C.} and Ian Streeter and Wildgoose, {Gregory G.} and Lawrence, {Nathan S.} and Li Jiang and Jones, {Timothy G. J.} and Compton, {Richard G.}",

year = "2004",

month = jul,

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doi = "10.1016/j.talanta.2004.01.017",

language = "English",

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journal = "Talanta",

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publisher = "Elsevier",

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TY - JOUR

T1 - Derivatized carbon powder electrodes: reagentless pH sensors

AU - Leventis, Henry C.

AU - Streeter, Ian

AU - Wildgoose, Gregory G.

AU - Lawrence, Nathan S.

AU - Jiang, Li

AU - Jones, Timothy G. J.

AU - Compton, Richard G.

PY - 2004/7/8

Y1 - 2004/7/8

N2 - The authors derivatize C powder with anthracene, azobenzene, diphenylamine, 9,10-diphenylanthracene, methylene blue, 3-nitrofluoranthene, 6-nitrochrysene, 9-nitroanthracene, 9,10-phenanthraquinone (PAQ), thionin, and fast black K (2,5-dimethoxy-4-[(4-nitrophenyl)azo]benzenediazonium chloride) and sep. immobilize the resulting material onto a bppg electrode. The authors use cyclic voltammetry (CV) to demonstrate that the obsd. voltammetric response for each derivatized C is consistent with that of an immobilized species. Further, the authors use CV and square wave voltammetry (SWV) to study the effect of pH on the peak potentials of each compd. studied over the range pH 1-12 and at elevated temps. up to 70° to demonstrate the versatility of derivatized C electrodes as reagentless pH sensors. [on SciFinder(R)]

AB - The authors derivatize C powder with anthracene, azobenzene, diphenylamine, 9,10-diphenylanthracene, methylene blue, 3-nitrofluoranthene, 6-nitrochrysene, 9-nitroanthracene, 9,10-phenanthraquinone (PAQ), thionin, and fast black K (2,5-dimethoxy-4-[(4-nitrophenyl)azo]benzenediazonium chloride) and sep. immobilize the resulting material onto a bppg electrode. The authors use cyclic voltammetry (CV) to demonstrate that the obsd. voltammetric response for each derivatized C is consistent with that of an immobilized species. Further, the authors use CV and square wave voltammetry (SWV) to study the effect of pH on the peak potentials of each compd. studied over the range pH 1-12 and at elevated temps. up to 70° to demonstrate the versatility of derivatized C electrodes as reagentless pH sensors. [on SciFinder(R)]

U2 - 10.1016/j.talanta.2004.01.017

DO - 10.1016/j.talanta.2004.01.017

M3 - Article

SN - 0039-9140

VL - 63

SP - 1039

EP - 1051

JO - Talanta

JF - Talanta

ER -