Dihydroisoquinolinium salts: catalysts for asymmetric epoxidation

Philip C. Bulman Page, Gerasimos A. Rassias, David Barros, Donald Bethell, Mark B. Schilling

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Abstract

A range of dihydroisoquinolinium salts has been prepared and tested as asymmetric epoxidation catalysts in an investigation of the reaction mechanism and the factors affecting enantioselectivity in this process.
Original languageEnglish
Pages (from-to)3325-3334
Number of pages10
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number19
DOIs
Publication statusPublished - 2000

Keywords

  • TWIN-CORONET PORPHYRINS
  • ALKENE EPOXIDATION
  • IMINIUM SALTS
  • SYNTHETIC ENZYMES
  • HIGHLY ENANTIOSELECTIVE EPOXIDATION
  • CHIRAL OXAZIRIDINIUM SALT
  • EFFICIENT
  • N-SULFONYLOXAZIRIDINES
  • OXYGEN-TRANSFER
  • UNFUNCTIONALIZED OLEFINS
  • EPOXIDATION

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