Dihydroisoquinolinium salts: catalysts for asymmetric epoxidation

Philip C. Bulman Page; Gerasimos A. Rassias; David Barros; Donald Bethell; Mark B. Schilling

doi:10.1039/b002156n

Dihydroisoquinolinium salts: catalysts for asymmetric epoxidation

Philip C. Bulman Page, Gerasimos A. Rassias, David Barros, Donald Bethell, Mark B. Schilling

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

A range of dihydroisoquinolinium salts has been prepared and tested as asymmetric epoxidation catalysts in an investigation of the reaction mechanism and the factors affecting enantioselectivity in this process.

Original language	English
Pages (from-to)	3325-3334
Number of pages	10
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	19
DOIs	https://doi.org/10.1039/b002156n
Publication status	Published - 2000

Keywords

TWIN-CORONET PORPHYRINS
ALKENE EPOXIDATION
IMINIUM SALTS
SYNTHETIC ENZYMES
HIGHLY ENANTIOSELECTIVE EPOXIDATION
CHIRAL OXAZIRIDINIUM SALT
EFFICIENT
N-SULFONYLOXAZIRIDINES
OXYGEN-TRANSFER
UNFUNCTIONALIZED OLEFINS
EPOXIDATION

Access to Document

10.1039/b002156n

Cite this

@article{2b934d7a50774da39bef40fff4923960,

title = "Dihydroisoquinolinium salts: catalysts for asymmetric epoxidation",

abstract = "A range of dihydroisoquinolinium salts has been prepared and tested as asymmetric epoxidation catalysts in an investigation of the reaction mechanism and the factors affecting enantioselectivity in this process.",

keywords = "TWIN-CORONET PORPHYRINS, ALKENE EPOXIDATION, IMINIUM SALTS, SYNTHETIC ENZYMES, HIGHLY ENANTIOSELECTIVE EPOXIDATION, CHIRAL OXAZIRIDINIUM SALT, EFFICIENT, N-SULFONYLOXAZIRIDINES, OXYGEN-TRANSFER, UNFUNCTIONALIZED OLEFINS, EPOXIDATION",

author = "{Bulman Page}, {Philip C.} and Rassias, {Gerasimos A.} and David Barros and Donald Bethell and Schilling, {Mark B.}",

year = "2000",

doi = "10.1039/b002156n",

language = "English",

pages = "3325--3334",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1472-7781",

publisher = "RSC Publishing",

number = "19",

}

TY - JOUR

T1 - Dihydroisoquinolinium salts: catalysts for asymmetric epoxidation

AU - Bulman Page, Philip C.

AU - Rassias, Gerasimos A.

AU - Barros, David

AU - Bethell, Donald

AU - Schilling, Mark B.

PY - 2000

Y1 - 2000

N2 - A range of dihydroisoquinolinium salts has been prepared and tested as asymmetric epoxidation catalysts in an investigation of the reaction mechanism and the factors affecting enantioselectivity in this process.

AB - A range of dihydroisoquinolinium salts has been prepared and tested as asymmetric epoxidation catalysts in an investigation of the reaction mechanism and the factors affecting enantioselectivity in this process.

KW - TWIN-CORONET PORPHYRINS

KW - ALKENE EPOXIDATION

KW - IMINIUM SALTS

KW - SYNTHETIC ENZYMES

KW - HIGHLY ENANTIOSELECTIVE EPOXIDATION

KW - CHIRAL OXAZIRIDINIUM SALT

KW - EFFICIENT

KW - N-SULFONYLOXAZIRIDINES

KW - OXYGEN-TRANSFER

KW - UNFUNCTIONALIZED OLEFINS

KW - EPOXIDATION

U2 - 10.1039/b002156n

DO - 10.1039/b002156n

M3 - Article

SN - 1472-7781

SP - 3325

EP - 3334

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 19

ER -