Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

Cristina Nieto-Oberhuber; Salomé López; Maria Munoz-Herranz; Diego J. Cárdenas; Elena Buñuel; Cristina Nevado; Antonio M. Echavarren

doi:10.1002/anie.200501937

Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

Cristina Nieto-Oberhuber, Salomé López, Maria Munoz-Herranz, Diego J. Cárdenas, Elena Buñuel, Cristina Nevado, Antonio M. Echavarren

Chemistry of Materials and Catalysis

Research output: Contribution to journal › Article › peer-review

272 Citations (Scopus)

Abstract

Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

Original language	English
Pages (from-to)	6146-6148
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	44
Issue number	38
DOIs	https://doi.org/10.1002/anie.200501937
Publication status	Published - 2005

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10.1002/anie.200501937

Cite this

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title = "Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold",

abstract = "Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes",

author = "Cristina Nieto-Oberhuber and Salom{\'e} L{\'o}pez and Maria Munoz-Herranz and C{\'a}rdenas, {Diego J.} and Elena Bu{\~n}uel and Cristina Nevado and Echavarren, {Antonio M.}",

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T1 - Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

AU - Nieto-Oberhuber, Cristina

AU - López, Salomé

AU - Munoz-Herranz, Maria

AU - Cárdenas, Diego J.

AU - Buñuel, Elena

AU - Nevado, Cristina

AU - Echavarren, Antonio M.

PY - 2005

Y1 - 2005

N2 - Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

AB - Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

U2 - 10.1002/anie.200501937

DO - 10.1002/anie.200501937

M3 - Article

VL - 44

SP - 6146

EP - 6148

JO - Angewandte Chemie-International Edition

JF - Angewandte Chemie-International Edition

SN - 1433-7851

IS - 38

ER -