Electroanalytical determination of cadmium(II) and lead(II) using an antimony nanoparticle modified boron-doped diamond electrode

Kathryn E. Toghill; Lei Xiao; Gregory Wildgoose; Richard G. Compton

doi:10.1002/elan.200904547

Electroanalytical determination of cadmium(II) and lead(II) using an antimony nanoparticle modified boron-doped diamond electrode

Kathryn E. Toghill, Lei Xiao, Gregory Wildgoose, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

153 Citations (Scopus)

Abstract

We report the simultaneous electroanalytical determination of Pb²⁺ and Cd²⁺ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb-BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L^-1 SbCl₃ in 0.1 M HCl (pH 1). Pb²⁺ inhibited the detection of Cd²⁺ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 µg L^-1.

Original language	English
Pages (from-to)	1113-1118
Number of pages	6
Journal	Electroanalysis
Volume	21
Issue number	10
DOIs	https://doi.org/10.1002/elan.200904547
Publication status	Published - 2009

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10.1002/elan.200904547

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title = "Electroanalytical determination of cadmium(II) and lead(II) using an antimony nanoparticle modified boron-doped diamond electrode",

abstract = "We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb-BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L-1 SbCl3 in 0.1 M HCl (pH 1). Pb2+ inhibited the detection of Cd2+ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 µg L-1.",

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T1 - Electroanalytical determination of cadmium(II) and lead(II) using an antimony nanoparticle modified boron-doped diamond electrode

AU - Toghill, Kathryn E.

AU - Xiao, Lei

AU - Wildgoose, Gregory

AU - Compton, Richard G.

PY - 2009

Y1 - 2009

N2 - We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb-BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L-1 SbCl3 in 0.1 M HCl (pH 1). Pb2+ inhibited the detection of Cd2+ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 µg L-1.

AB - We report the simultaneous electroanalytical determination of Pb2+ and Cd2+ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb-BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L-1 SbCl3 in 0.1 M HCl (pH 1). Pb2+ inhibited the detection of Cd2+ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 µg L-1.

U2 - 10.1002/elan.200904547

DO - 10.1002/elan.200904547

M3 - Article

SN - 1521-4109

VL - 21

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EP - 1118

JO - Electroanalysis

JF - Electroanalysis

IS - 10

ER -