Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide

Gregory G. Wildgoose; Debora Giovanelli; Oleksiy V. Klymenko; Nathan S. Lawrence; Li Jiang; Timothy G. J. Jones; Richard G. Compton

doi:10.1002/elan.200302859

Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide

Gregory G. Wildgoose, Debora Giovanelli, Oleksiy V. Klymenko, Nathan S. Lawrence, Li Jiang, Timothy G. J. Jones, Richard G. Compton

School of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The electrochem. oxidn. of DEPD proceeds via an ECrevECE mechanism in DMF. It has been investigated at elevated temps. up to 130°C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodn. parameters for the reaction process have been calcd. for each temp. Further, the voltammetric response of DEPD shows enhanced limiting currents in the presence of sulfide. The anal. utility of the approach has been investigated with linear range from 50 to 850 µM sulfide concn. obsd. and a corresponding limit of detection of 20 µM achievable at temps. of 70°C. [on SciFinder(R)]

Original language	English
Pages (from-to)	337-344
Number of pages	8
Journal	Electroanalysis
Volume	16
DOIs	https://doi.org/10.1002/elan.200302859
Publication status	Published - 2004

Keywords

sulfide electrochem detn diethylphenylenediamine reaction

Access to Document

10.1002/elan.200302859

Cite this

@article{7d409e70b2514b328ce350b35d42bfca,

title = "Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide",

abstract = "The electrochem. oxidn. of DEPD proceeds via an ECrevECE mechanism in DMF. It has been investigated at elevated temps. up to 130°C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodn. parameters for the reaction process have been calcd. for each temp. Further, the voltammetric response of DEPD shows enhanced limiting currents in the presence of sulfide. The anal. utility of the approach has been investigated with linear range from 50 to 850 µM sulfide concn. obsd. and a corresponding limit of detection of 20 µM achievable at temps. of 70°C. [on SciFinder(R)]",

keywords = "sulfide electrochem detn diethylphenylenediamine reaction",

author = "Wildgoose, {Gregory G.} and Debora Giovanelli and Klymenko, {Oleksiy V.} and Lawrence, {Nathan S.} and Li Jiang and Jones, {Timothy G. J.} and Compton, {Richard G.}",

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language = "English",

volume = "16",

pages = "337--344",

journal = "Electroanalysis",

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publisher = "Wiley",

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Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide. / Wildgoose, Gregory G.; Giovanelli, Debora; Klymenko, Oleksiy V.; Lawrence, Nathan S.; Jiang, Li; Jones, Timothy G. J.; Compton, Richard G.

In: Electroanalysis, Vol. 16, 2004, p. 337-344.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical determination of sulfide at high temperatures via its electrochemically initiated reaction with diethyl-p-phenylenediamine in dimethylformamide

AU - Wildgoose, Gregory G.

AU - Giovanelli, Debora

AU - Klymenko, Oleksiy V.

AU - Lawrence, Nathan S.

AU - Jiang, Li

AU - Jones, Timothy G. J.

AU - Compton, Richard G.

PY - 2004

Y1 - 2004

N2 - The electrochem. oxidn. of DEPD proceeds via an ECrevECE mechanism in DMF. It has been investigated at elevated temps. up to 130°C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodn. parameters for the reaction process have been calcd. for each temp. Further, the voltammetric response of DEPD shows enhanced limiting currents in the presence of sulfide. The anal. utility of the approach has been investigated with linear range from 50 to 850 µM sulfide concn. obsd. and a corresponding limit of detection of 20 µM achievable at temps. of 70°C. [on SciFinder(R)]

AB - The electrochem. oxidn. of DEPD proceeds via an ECrevECE mechanism in DMF. It has been investigated at elevated temps. up to 130°C at both micro and macro platinum and glassy carbon electrodes. Kinetic and thermodn. parameters for the reaction process have been calcd. for each temp. Further, the voltammetric response of DEPD shows enhanced limiting currents in the presence of sulfide. The anal. utility of the approach has been investigated with linear range from 50 to 850 µM sulfide concn. obsd. and a corresponding limit of detection of 20 µM achievable at temps. of 70°C. [on SciFinder(R)]

KW - sulfide electrochem detn diethylphenylenediamine reaction

U2 - 10.1002/elan.200302859

DO - 10.1002/elan.200302859

M3 - Article

VL - 16

SP - 337

EP - 344

JO - Electroanalysis

JF - Electroanalysis

SN - 1040-0397

ER -