Fighting Fenton Chemistry: A highly active iron(III) tetracarbene complex in epoxidation catalysis

Jens W. Kück, Markus R. Anneser, Benjamin Hofmann, Alexander Pöthig, Mirza Cokoja, Fritz E. Kühn

Research output: Contribution to journalArticlepeer-review

48 Citations (Scopus)

Abstract

Organometallic Fe complexes with exceptionally high activities in homogeneous epoxidation catalysis are reported. The compounds display FeII and FeIII oxidation states and bear a tetracarbene ligand. The more active catalyst exhibits activities up to 183 000 turnovers per hour at room temperature and turnover numbers of up to 4300 at -30°C. For the FeIII complex, a decreased Fenton-type reactivity is observed compared with FeII catalysts reported previously as indicated by a substantially lower H2O2 decomposition and higher (initial) turnover frequencies. The dependence of the catalyst performance on the catalyst loading, substrate, water addition, and the oxidant is investigated. Under all applied conditions, the advantageous nature of the use of the FeIII complex is evident.

Original languageEnglish
Pages (from-to)4056-4063
Number of pages8
JournalChemSusChem
Volume8
Issue number23
Early online date17 Nov 2015
DOIs
Publication statusPublished - 7 Dec 2015

Keywords

  • carbene ligands
  • epoxidation
  • homogeneous catalysis
  • iron
  • peroxides

Cite this