Four geranyl-bearing polyisoprenylated benzoylphloroglucinol derivatives from Hypericum sampsonii

Yi Han Zeng, Khadijo Osman, Zhi Yong Xiao, Simon Gibbons, Qing Mu

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22 Citations (Scopus)

Abstract

Four new geranyl-bearing polyisoprenylated benzoylphloroglucinol derivatives, hypersampsone I (1), hypersampsone J (2), and hypersampsone K (3), together with hypersampsone L (4) which possessed a novel skeleton, were isolated from the fruit of Hypericum sampsonii. Their structures were determined on the basis of spectroscopic data, mainly 1D- and 2D-NMR spectroscopy and mass spectrometry. The structures of 1 and 2 were confirmed by X-ray crystallographic analysis.

Original languageEnglish
Pages (from-to)200-205
Number of pages6
JournalPhytochemistry Letters
Volume5
Issue number1
DOIs
Publication statusPublished - Mar 2012

Keywords

  • Hypericum
  • Hypericum sampsonii
  • Hypersampsone H
  • Hypersampsone I-L
  • Polyisoprenylated benzoylphloroglucinol derivatives
  • X-ray crystallography

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