TY - JOUR
T1 - Further observations of the 460 nm band system of nickel dichloride, cooled to lower temperatures in a free jet expansion
AU - Ashworth, Stephen
PY - 1990
Y1 - 1990
N2 - The 460 nm band system of NiCl2, formed in a free jet expansion, has been recorded under colder conditions than achieved previously by a simple modification of the heated nozzle source. The spectrum is considerably simplified, permitting several weak, new features to be observed. In particular, bands which involve the excitation of two additional quanta of the bending vibration ?2 in the upper state are observed, yielding values for Image '2 and Image ?2 of 61.1 and 87.1 cm-1, respectively. The origin of the fine-structure splitting and the ordering of the spin components is also determinable from this spectrum. Weak features which may be sequence bands in the antisymmetric stretching vibration ?3 have also been observed.
AB - The 460 nm band system of NiCl2, formed in a free jet expansion, has been recorded under colder conditions than achieved previously by a simple modification of the heated nozzle source. The spectrum is considerably simplified, permitting several weak, new features to be observed. In particular, bands which involve the excitation of two additional quanta of the bending vibration ?2 in the upper state are observed, yielding values for Image '2 and Image ?2 of 61.1 and 87.1 cm-1, respectively. The origin of the fine-structure splitting and the ordering of the spin components is also determinable from this spectrum. Weak features which may be sequence bands in the antisymmetric stretching vibration ?3 have also been observed.
U2 - 10.1016/0009-2614(90)85599-8
DO - 10.1016/0009-2614(90)85599-8
M3 - Article
VL - 175
SP - 660
EP - 666
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 6
ER -