Gold(III) olefin complexes

Nicky Savjani; Dragoş-Adrian Roşca; Mark Schormann; Manfred Bochmann

doi:10.1002/anie.201208356

Gold(III) olefin complexes

Nicky Savjani, Dragoş-Adrian Roşca, Mark Schormann, Manfred Bochmann

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76 Citations (Scopus)

Abstract

Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for Au-Ag interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	874-877
Number of pages	4
Journal	Angewandte Chemie-International Edition
Volume	52
Issue number	3
Early online date	23 Nov 2012
DOIs	https://doi.org/10.1002/anie.201208356
Publication status	Published - 14 Jan 2013

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abstract = "Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for Au-Ag interactions. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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Gold(III) olefin complexes

Abstract

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