Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine

Gregory G. Wildgoose; Shelley J. Wilkins; Gareth R. Williams; Robert R. France; David L. Carnahan; Jiang Li; Timothy G. J. Jones; Richard G. Compton

doi:10.1002/cphc.200400403

Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine

Gregory G. Wildgoose
, Shelley J. Wilkins
, Gareth R. Williams
, Robert R. France
, David L. Carnahan
, Jiang Li
, Timothy G. J. Jones
, Richard G. Compton

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatized by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a soln. of acetonitrile contg. 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localized edge-plane or edge-plane-like defect sites and support this hypothesis with a range of exptl. data provided by electrochem. in both aq. and nonaq. media, electron microscopy and X-ray powder diffraction. [on SciFinder(R)]

Original language	English
Pages (from-to)	352-362
Number of pages	11
Journal	ChemPhysChem
Volume	6
DOIs	https://doi.org/10.1002/cphc.200400403
Publication status	Published - 2005

Keywords

graphite carbon nanotube nitrobenzylamine intercalation electrode

Access to Document

10.1002/cphc.200400403

Cite this

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title = "Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine",

abstract = "We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatized by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a soln. of acetonitrile contg. 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localized edge-plane or edge-plane-like defect sites and support this hypothesis with a range of exptl. data provided by electrochem. in both aq. and nonaq. media, electron microscopy and X-ray powder diffraction. [on SciFinder(R)]",

keywords = "graphite carbon nanotube nitrobenzylamine intercalation electrode",

author = "Wildgoose, \{Gregory G.\} and Wilkins, \{Shelley J.\} and Williams, \{Gareth R.\} and France, \{Robert R.\} and Carnahan, \{David L.\} and Jiang Li and Jones, \{Timothy G. J.\} and Compton, \{Richard G.\}",

year = "2005",

doi = "10.1002/cphc.200400403",

language = "English",

volume = "6",

pages = "352--362",

journal = "ChemPhysChem",

issn = "1439-4235",

publisher = "Wiley",

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TY - JOUR

T1 - Graphite powder and multiwalled carbon nanotubes chemically modified with 4-nitrobenzylamine

AU - Wildgoose, Gregory G.

AU - Wilkins, Shelley J.

AU - Williams, Gareth R.

AU - France, Robert R.

AU - Carnahan, David L.

AU - Li, Jiang

AU - Jones, Timothy G. J.

AU - Compton, Richard G.

PY - 2005

Y1 - 2005

N2 - We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatized by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a soln. of acetonitrile contg. 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localized edge-plane or edge-plane-like defect sites and support this hypothesis with a range of exptl. data provided by electrochem. in both aq. and nonaq. media, electron microscopy and X-ray powder diffraction. [on SciFinder(R)]

AB - We demonstrate that graphite powder and multiwalled carbon nanotubes (MWCNTs) can be derivatized by 4-nitrobenzylamine (4-NBA) simply by stirring the graphite powder or MWCNTs in a soln. of acetonitrile contg. 10 mM 4-NBA. We propose that 4-NBA partially intercalates at localized edge-plane or edge-plane-like defect sites and support this hypothesis with a range of exptl. data provided by electrochem. in both aq. and nonaq. media, electron microscopy and X-ray powder diffraction. [on SciFinder(R)]

KW - graphite carbon nanotube nitrobenzylamine intercalation electrode

U2 - 10.1002/cphc.200400403

DO - 10.1002/cphc.200400403

M3 - Article

SN - 1439-4235

VL - 6

SP - 352

EP - 362

JO - ChemPhysChem

JF - ChemPhysChem

ER -