High Carrier Mobility up to 1.4 cm2·V-1·s-1in Non-Peripheral Octahexyl Phthalocyanine

Yasuo Miyake; Youyu Shiraiwa; Keizo Okada; Hirosato Monobe; Tetsuro Hori; Naoyuki Yamasaki; Hiroyuki Yoshida; Mike Cook; Akihiko Fujii; Masanori Ozaki; Yo Shimizu

doi:10.1143/APEX.4.021604

High Carrier Mobility up to 1.4 cm2·V-1·s-1in Non-Peripheral Octahexyl Phthalocyanine

Yasuo Miyake, Youyu Shiraiwa, Keizo Okada, Hirosato Monobe, Tetsuro Hori, Naoyuki Yamasaki, Hiroyuki Yoshida, Mike Cook, Akihiko Fujii, Masanori Ozaki, Yo Shimizu

School of Chemistry

Research output: Contribution to journal › Article › peer-review

101 Citations (Scopus)

Abstract

Carrier transport properties of a non-peripherally alkyl-substituted phthalocyanine, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH₂) have been investigated. The material is a low-molecular-weight organic semiconductor with high solubility for typical organic solvents and liquid crystallinity. The carrier mobility was measured in the crystal phase and the hexagonal disordered columnar (Col_hd) mesophase by the time-of-flight technique. A strong negative temperature dependence was observed for the hole mobility in the crystal phase, and a maximum drift mobility of 1.4 cm²·V^-1·s^-1 was achieved at -15 °C. A maximum mobility of 0.5 cm²·V^-1·s^-1 was obtained for the electrons that had a smaller dependence.

Original language	English
Article number	021604
Journal	Applied Physics Express
Volume	4
Issue number	2
DOIs	https://doi.org/10.1143/APEX.4.021604
Publication status	Published - 21 Jan 2011

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10.1143/APEX.4.021604

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@article{8cfb4d60097a426c99a23ef78053ba6f,

title = "High Carrier Mobility up to 1.4 cm2·V-1·s-1in Non-Peripheral Octahexyl Phthalocyanine",

abstract = "Carrier transport properties of a non-peripherally alkyl-substituted phthalocyanine, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2) have been investigated. The material is a low-molecular-weight organic semiconductor with high solubility for typical organic solvents and liquid crystallinity. The carrier mobility was measured in the crystal phase and the hexagonal disordered columnar (Colhd) mesophase by the time-of-flight technique. A strong negative temperature dependence was observed for the hole mobility in the crystal phase, and a maximum drift mobility of 1.4 cm2·V-1·s-1 was achieved at -15 °C. A maximum mobility of 0.5 cm2·V-1·s-1 was obtained for the electrons that had a smaller dependence.",

author = "Yasuo Miyake and Youyu Shiraiwa and Keizo Okada and Hirosato Monobe and Tetsuro Hori and Naoyuki Yamasaki and Hiroyuki Yoshida and Mike Cook and Akihiko Fujii and Masanori Ozaki and Yo Shimizu",

year = "2011",

month = jan,

day = "21",

doi = "10.1143/APEX.4.021604",

language = "English",

volume = "4",

journal = "Applied Physics Express",

issn = "1882-0778",

publisher = "Japan Society of Applied Physics",

number = "2",

}

High Carrier Mobility up to 1.4 cm2·V-1·s-1in Non-Peripheral Octahexyl Phthalocyanine. / Miyake, Yasuo; Shiraiwa, Youyu; Okada, Keizo; Monobe, Hirosato; Hori, Tetsuro; Yamasaki, Naoyuki; Yoshida, Hiroyuki; Cook, Mike; Fujii, Akihiko; Ozaki, Masanori; Shimizu, Yo.

In: Applied Physics Express, Vol. 4, No. 2, 021604, 21.01.2011.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - High Carrier Mobility up to 1.4 cm2·V-1·s-1in Non-Peripheral Octahexyl Phthalocyanine

AU - Miyake, Yasuo

AU - Shiraiwa, Youyu

AU - Okada, Keizo

AU - Monobe, Hirosato

AU - Hori, Tetsuro

AU - Yamasaki, Naoyuki

AU - Yoshida, Hiroyuki

AU - Cook, Mike

AU - Fujii, Akihiko

AU - Ozaki, Masanori

AU - Shimizu, Yo

PY - 2011/1/21

Y1 - 2011/1/21

N2 - Carrier transport properties of a non-peripherally alkyl-substituted phthalocyanine, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2) have been investigated. The material is a low-molecular-weight organic semiconductor with high solubility for typical organic solvents and liquid crystallinity. The carrier mobility was measured in the crystal phase and the hexagonal disordered columnar (Colhd) mesophase by the time-of-flight technique. A strong negative temperature dependence was observed for the hole mobility in the crystal phase, and a maximum drift mobility of 1.4 cm2·V-1·s-1 was achieved at -15 °C. A maximum mobility of 0.5 cm2·V-1·s-1 was obtained for the electrons that had a smaller dependence.

AB - Carrier transport properties of a non-peripherally alkyl-substituted phthalocyanine, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH2) have been investigated. The material is a low-molecular-weight organic semiconductor with high solubility for typical organic solvents and liquid crystallinity. The carrier mobility was measured in the crystal phase and the hexagonal disordered columnar (Colhd) mesophase by the time-of-flight technique. A strong negative temperature dependence was observed for the hole mobility in the crystal phase, and a maximum drift mobility of 1.4 cm2·V-1·s-1 was achieved at -15 °C. A maximum mobility of 0.5 cm2·V-1·s-1 was obtained for the electrons that had a smaller dependence.

U2 - 10.1143/APEX.4.021604

DO - 10.1143/APEX.4.021604

M3 - Article

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JO - Applied Physics Express

JF - Applied Physics Express

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