High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene

Jia-Xing Jiang; Andrea Laybourn; Rob Clowes; Yaroslav Z. Khimyak; John Bacsa; Simon J. Higgins; Dave J. Adams; Andrew I. Cooper

doi:10.1021/ma101468r

High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene

Jia-Xing Jiang, Andrea Laybourn, Rob Clowes, Yaroslav Z. Khimyak, John Bacsa, Simon J. Higgins, Dave J. Adams, Andrew I. Cooper

Pharmaceutical Materials and Soft Matter

Research output: Contribution to journal › Article › peer-review

113 Citations (Scopus)

Abstract

Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

Original language	English
Pages (from-to)	7577-7582
Number of pages	6
Journal	Macromolecules
Volume	43
Issue number	18
DOIs	https://doi.org/10.1021/ma101468r
Publication status	Published - 2010

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10.1021/ma101468r

Cite this

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title = "High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene",

abstract = "Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.",

author = "Jia-Xing Jiang and Andrea Laybourn and Rob Clowes and Khimyak, {Yaroslav Z.} and John Bacsa and Higgins, {Simon J.} and Adams, {Dave J.} and Cooper, {Andrew I.}",

year = "2010",

doi = "10.1021/ma101468r",

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T1 - High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene

AU - Jiang, Jia-Xing

AU - Laybourn, Andrea

AU - Clowes, Rob

AU - Khimyak, Yaroslav Z.

AU - Bacsa, John

AU - Higgins, Simon J.

AU - Adams, Dave J.

AU - Cooper, Andrew I.

PY - 2010

Y1 - 2010

N2 - Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

AB - Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.

U2 - 10.1021/ma101468r

DO - 10.1021/ma101468r

M3 - Article

SN - 0024-9297

VL - 43

SP - 7577

EP - 7582

JO - Macromolecules

JF - Macromolecules

IS - 18

ER -