Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Alexander S. Romanov; Dawei Di; Le Yang; Julio Fernandez-Cestau; Ciaran R. Becker; Charlotte E. James; Bonan Zhu; Mikko Linnolahti; Dan Credgington; Manfred Bochmann

doi:10.1039/C6CC02349E

Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Alexander S. Romanov, Dawei Di, Le Yang, Julio Fernandez-Cestau, Ciaran R. Becker, Charlotte E. James, Bonan Zhu, Mikko Linnolahti, Dan Credgington, Manfred Bochmann

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Abstract

Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

Original language	English
Pages (from-to)	6379-6382
Journal	Chemical Communications
Volume	52
Issue number	38
Early online date	12 Apr 2016
DOIs	https://doi.org/10.1039/C6CC02349E https://doi.org/10.1039/C8CC90135J
Publication status	Published - 11 May 2016

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10.1039/C6CC02349ELicence: CC BY
10.1039/C8CC90135JLicence: CC BY

Chem Commun. 2016, 52, 6379Final published version, 1.71 MBLicence: CC BY

Gold(III) Chemistry: Structures, Bonding, Reactivity and Catalysis
Bochmann, M.
CEC (Framework 7)
1/02/14 → 31/01/19
Project: Research

Cite this

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title = "Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence",

abstract = "Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.",

author = "Romanov, {Alexander S.} and Dawei Di and Le Yang and Julio Fernandez-Cestau and Becker, {Ciaran R.} and James, {Charlotte E.} and Bonan Zhu and Mikko Linnolahti and Dan Credgington and Manfred Bochmann",

note = "Correction available at dx.doi.org/10.1039/C8CC90135J",

year = "2016",

month = may,

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doi = "10.1039/C6CC02349E",

language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

AU - Romanov, Alexander S.

AU - Di, Dawei

AU - Yang, Le

AU - Fernandez-Cestau, Julio

AU - Becker, Ciaran R.

AU - James, Charlotte E.

AU - Zhu, Bonan

AU - Linnolahti, Mikko

AU - Credgington, Dan

AU - Bochmann, Manfred

N1 - Correction available at dx.doi.org/10.1039/C8CC90135J

PY - 2016/5/11

Y1 - 2016/5/11

N2 - Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

AB - Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

U2 - 10.1039/C6CC02349E

DO - 10.1039/C6CC02349E

M3 - Article

VL - 52

SP - 6379

EP - 6382

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 38

ER -

Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Abstract

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Projects

Gold(III) Chemistry: Structures, Bonding, Reactivity and Catalysis

Cite this