Host-guest interactions: ferrocene in KY zeolite

C. T. Kaiser, P. C. M. Gubbens, E. Kemner, A. R. Overweg, U. A. Jayasooriya, S. P. Cottrell

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    Abstract

    Host-guest interactions of ferrocene in KY zeolite were investigated using muon spin relaxation (muSR). Temperature-dependent measurements enable us the determination of the activation parameters for the low energy dynamic processes of,the encapsulated ferrocene. A comparison between the pSR results and the earlier neutron measurements illustrates the advantage of the former technique for probing the lowest unoccupied molecular orbital (LUMO). (C) 2003 Elsevier B.V. All rights reserved.
    Original languageEnglish
    Pages (from-to)292-297
    Number of pages6
    JournalChemical Physics Letters
    Volume381
    Issue number3-4
    DOIs
    Publication statusPublished - 2003

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