H2 activation using the first 1:1:1 hetero-tri(aryl)borane

Robin J. Blagg; Gregory G. Wildgoose

doi:10.1039/C6RA07007H

H₂ activation using the first 1:1:1 hetero-tri(aryl)borane

Robin J. Blagg (Lead Author), Gregory G. Wildgoose

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

21 Downloads (Pure)

Abstract

The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.

Original language	English
Pages (from-to)	42421-42427
Journal	RSC Advances
Volume	6
Issue number	48
DOIs	https://doi.org/10.1039/C6RA07007H
Publication status	Published - 28 Apr 2016

Access to Document

10.1039/C6RA07007HLicence: CC BY

BW2016Final published version, 794 KBLicence: CC BY
BW2016_SIFinal published version, 1.36 MBLicence: CC BY

(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions
Wildgoose, G. & Blagg, R.
CEC (Framework 7)
1/08/12 → 31/07/17
Project: Research

Cite this

@article{291547d8db89499b9ae0a2ed39167aca,

title = "H2 activation using the first 1:1:1 hetero-tri(aryl)borane",

abstract = "The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.",

author = "Blagg, {Robin J.} and Wildgoose, {Gregory G.}",

note = "This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. ",

year = "2016",

month = apr,

day = "28",

doi = "10.1039/C6RA07007H",

language = "English",

volume = "6",

pages = "42421--42427",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "48",

}

TY - JOUR

T1 - H2 activation using the first 1:1:1 hetero-tri(aryl)borane

AU - Blagg, Robin J.

AU - Wildgoose, Gregory G.

N1 - This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

PY - 2016/4/28

Y1 - 2016/4/28

N2 - The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.

AB - The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.

U2 - 10.1039/C6RA07007H

DO - 10.1039/C6RA07007H

M3 - Article

SN - 2046-2069

VL - 6

SP - 42421

EP - 42427

JO - RSC Advances

JF - RSC Advances

IS - 48

ER -

H2 activation using the first 1:1:1 hetero-tri(aryl)borane

Abstract

Access to Document

Projects

(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions

Cite this

H₂ activation using the first 1:1:1 hetero-tri(aryl)borane