H2 activation using the first 1:1:1 hetero-tri(aryl)borane

Robin J. Blagg; Gregory G. Wildgoose

doi:10.1039/C6RA07007H

H₂ activation using the first 1:1:1 hetero-tri(aryl)borane

Robin J. Blagg (Lead Author)
, Gregory G. Wildgoose

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

28 Downloads (Pure)

Abstract

The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.

Original language	English
Pages (from-to)	42421-42427
Journal	RSC Advances
Volume	6
Issue number	48
DOIs	https://doi.org/10.1039/C6RA07007H
Publication status	Published - 28 Apr 2016

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10.1039/C6RA07007HLicence: CC BY

BW2016Final published version, 794 KBLicence: CC BY
BW2016_SIFinal published version, 1.36 MBLicence: CC BY

(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions
Wildgoose, G. (Principal Investigator) & Blagg, R. (Researcher)
CEC (Framework 7)
1/08/12 → 31/07/17
Project: Research

Cite this

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title = "H2 activation using the first 1:1:1 hetero-tri(aryl)borane",

abstract = "The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl)\{3,5-bis(trifluoromethyl)phenyl\}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H2 with three Lewis bases.",

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H2 activation using the first 1:1:1 hetero-tri(aryl)borane

Abstract

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Projects

(PiHOMER) Pioneering Heterogeneous Organometallic-Mediated Electrocatalytic Reactions

Cite this

H₂ activation using the first 1:1:1 hetero-tri(aryl)borane