Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation

Takehiko Yamato; Carol Pérez-Casas; Akina Yoshizawa; Shofuir Rahman; Mark R. J. Elsegood; Carl Redshaw

doi:10.1007/s10847-008-9523-4

Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation

Takehiko Yamato, Carol Pérez-Casas, Akina Yoshizawa, Shofuir Rahman, Mark R. J. Elsegood, Carl Redshaw

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Novel ditopic receptors of tetraamide derivatives possessing four 2-pyridyl groups derived from thiacalix[4]arene in cone- and 1,3-alternate conformation were prepared. The structure of one of the tetraamide derivatives was confirmed by a single crystal X-ray analysis. The tetrathiacalix[4]arene tetraamides show strong intramolecular hydrogen bonding. The binding behaviour towards Ag+ and halides has been investigated by 1H NMR titration experiments.

Original language	English
Pages (from-to)	301-308
Number of pages	8
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	63
Issue number	3
Early online date	17 Dec 2008
DOIs	https://doi.org/10.1007/s10847-008-9523-4
Publication status	Published - Apr 2009

Keywords

Thiacalix[4]arene
O-alkylation
Conformation
Ionophores
Hydrogen bond
Metal complexation

Access to Document

10.1007/s10847-008-9523-4

Cite this

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title = "Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation",

abstract = "Novel ditopic receptors of tetraamide derivatives possessing four 2-pyridyl groups derived from thiacalix[4]arene in cone- and 1,3-alternate conformation were prepared. The structure of one of the tetraamide derivatives was confirmed by a single crystal X-ray analysis. The tetrathiacalix[4]arene tetraamides show strong intramolecular hydrogen bonding. The binding behaviour towards Ag+ and halides has been investigated by 1H NMR titration experiments.",

keywords = "Thiacalix[4]arene, O-alkylation, Conformation, Ionophores, Hydrogen bond, Metal complexation",

author = "Takehiko Yamato and Carol P{\'e}rez-Casas and Akina Yoshizawa and Shofuir Rahman and Elsegood, {Mark R. J.} and Carl Redshaw",

year = "2009",

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doi = "10.1007/s10847-008-9523-4",

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journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

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T1 - Hydrogen bonding receptors of tetraamide derivatives derived from thiacalix[4]arene in cone- and 1,3-alternate conformation

AU - Yamato, Takehiko

AU - Pérez-Casas, Carol

AU - Yoshizawa, Akina

AU - Rahman, Shofuir

AU - Elsegood, Mark R. J.

AU - Redshaw, Carl

PY - 2009/4

Y1 - 2009/4

N2 - Novel ditopic receptors of tetraamide derivatives possessing four 2-pyridyl groups derived from thiacalix[4]arene in cone- and 1,3-alternate conformation were prepared. The structure of one of the tetraamide derivatives was confirmed by a single crystal X-ray analysis. The tetrathiacalix[4]arene tetraamides show strong intramolecular hydrogen bonding. The binding behaviour towards Ag+ and halides has been investigated by 1H NMR titration experiments.

AB - Novel ditopic receptors of tetraamide derivatives possessing four 2-pyridyl groups derived from thiacalix[4]arene in cone- and 1,3-alternate conformation were prepared. The structure of one of the tetraamide derivatives was confirmed by a single crystal X-ray analysis. The tetrathiacalix[4]arene tetraamides show strong intramolecular hydrogen bonding. The binding behaviour towards Ag+ and halides has been investigated by 1H NMR titration experiments.

KW - Thiacalix[4]arene

KW - O-alkylation

KW - Conformation

KW - Ionophores

KW - Hydrogen bond

KW - Metal complexation

U2 - 10.1007/s10847-008-9523-4

DO - 10.1007/s10847-008-9523-4

M3 - Article

SN - 0923-0750

VL - 63

SP - 301

EP - 308

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 3

ER -